Perfume systems

ABSTRACT

The present application relates to perfume raw materials, perfume delivery systems and consumer products comprising such perfume raw materials and/or such perfume delivery systems, as well as processes for making and using such perfume raw materials, perfume delivery systems and consumer products. Such perfume raw materials and compositions, including the delivery systems, disclosed herein expand the perfume communities&#39; options as such perfume raw materials can provide variations on character and such compositions can provide desired odor profiles.

FIELD OF INVENTION

The present application relates to perfume raw materials, perfumedelivery systems and consumer products comprising such perfume rawmaterials and/or perfume delivery systems, as well as processes formaking and using such perfume raw materials, perfume delivery systemsand consumer products.

BACKGROUND OF THE INVENTION

Consumer products may comprise one or more perfumes and/or perfumedelivery systems that can mask an undesirable odor and/or provide adesired scent to a product and/or a situs that is contacted with such aproduct. While current perfumes and perfume delivery systems providedesirable fragrances, consumers continue to seek products that havescents that may be longer lasting and that are tailored to theirindividual desires (see for example USPA 20070275866 A1 and USPA20080305977 A1)—unfortunately the pool of perfume raw materials andperfume delivery systems that is available is still too limited tocompletely meet the perfume community's needs. Thus, perfumers need anever larger pool of perfume raw materials and perfume delivery systems.

Applicants believe that the perfume raw materials and perfumes,including the delivery systems, disclosed herein expand the perfumecommunity's options, as such perfume raw materials can providevariations on character and such perfumes can provide desired odorprofiles. In certain aspects, such perfume raw materials and/or perfumedelivery systems comprising such perfume raw materials may providevariations on character and/or odor profiles that are better thanexpected as measured by parameters such as headspace analysis (employedto determine perfume delivery system perfume leakage and/or perfumedelivery efficiency), ClogP, boiling point and/or odor detectionthreshold.

SUMMARY OF THE INVENTION

The present application relates to perfume raw materials, perfumedelivery systems and consumer products comprising such perfume rawmaterials and/or such perfume delivery systems, as well as processes formaking and using such perfume raw materials, perfume delivery systemsand consumer products.

DETAILED DESCRIPTION OF THE INVENTION Definitions

As used herein “consumer product” means baby care, beauty care, fabric &home care, family care, feminine care, health care, snack and/orbeverage products or devices generally intended to be used or consumedin the form in which it is sold. Such products include but are notlimited to diapers, bibs, wipes; products for and/or methods relating totreating hair (human, dog, and/or cat), including, bleaching, coloring,dyeing, conditioning, shampooing, styling; deodorants andantiperspirants; personal cleansing; cosmetics; skin care includingapplication of creams, lotions, and other topically applied products forconsumer use including fine fragrances; and shaving products, productsfor and/or methods relating to treating fabrics, hard surfaces and anyother surfaces in the area of fabric and home care, including: air careincluding air fresheners and scent delivery systems, car care,dishwashing, fabric conditioning (including softening and/orfreshening), laundry detergency, laundry and rinse additive and/or care,hard surface cleaning and/or treatment including floor and toilet bowlcleaners, and other cleaning for consumer or institutional use; productsand/or methods relating to bath tissue, facial tissue, paperhandkerchiefs, and/or paper towels; tampons, feminine napkins; productsand/or methods relating to oral care including toothpastes, tooth gels,tooth rinses, denture adhesives, tooth whitening; over-the-counterhealth care including cough and cold remedies, pain relievers, RXpharmaceuticals, pet health and nutrition; processed food productsintended primarily for consumption between customary meals or as a mealaccompaniment (non-limiting examples include potato chips, tortillachips, popcorn, pretzels, corn chips, cereal bars, vegetable chips orcrisps, snack mixes, party mixes, multigrain chips, snack crackers,cheese snacks, pork rinds, corn snacks, pellet snacks, extruded snacksand bagel chips); and coffee.

As used herein, the term “cleaning and/or treatment composition” is asubset of consumer products that includes, unless otherwise indicated,beauty care, fabric & home care products. Such products include, but arenot limited to, products for treating hair (human, dog, and/or cat),including, bleaching, coloring, dyeing, conditioning, shampooing,styling; deodorants and antiperspirants; personal cleansing; cosmetics;skin care including application of creams, lotions, and other topicallyapplied products for consumer use including fine fragrances; and shavingproducts, products for treating fabrics, hard surfaces and any othersurfaces in the area of fabric and home care, including: air careincluding air fresheners and scent delivery systems, car care,dishwashing, fabric conditioning (including softening and/orfreshening), laundry detergency, laundry and rinse additive and/or care,hard surface cleaning and/or treatment including floor and toilet bowlcleaners, granular or powder-form all-purpose or “heavy-duty” washingagents, especially cleaning detergents; liquid, gel or paste-formall-purpose washing agents, especially the so-called heavy-duty liquidtypes; liquid fine-fabric detergents; hand dishwashing agents or lightduty dishwashing agents, especially those of the high-foaming type;machine dishwashing agents, including the various tablet, granular,liquid and rinse-aid types for household and institutional use; liquidcleaning and disinfecting agents, including antibacterial hand-washtypes, cleaning bars, mouthwashes, denture cleaners, dentifrice, car orcarpet shampoos, bathroom cleaners including toilet bowl cleaners; hairshampoos and hair-rinses; shower gels, fine fragrances and foam bathsand metal cleaners; as well as cleaning auxiliaries such as bleachadditives and “stain-stick” or pre-treat types, substrate-laden productssuch as dryer added sheets, dry and wetted wipes and pads, nonwovensubstrates, and sponges; as well as sprays and mists all for consumeror/and institutional use; and/or methods relating to oral care includingtoothpastes, tooth gels, tooth rinses, denture adhesives, toothwhitening.As used herein, the term “fabric and/or hard surface cleaning and/ortreatment composition” is a subset of cleaning and treatmentcompositions that includes, unless otherwise indicated, granular orpowder-form all-purpose or “heavy-duty” washing agents, especiallycleaning detergents; liquid, gel or paste-form all-purpose washingagents, especially the so-called heavy-duty liquid types; liquidfine-fabric detergents; hand dishwashing agents or light dutydishwashing agents, especially those of the high-foaming type; machinedishwashing agents, including the various tablet, granular, liquid andrinse-aid types for household and institutional use; liquid cleaning anddisinfecting agents, including antibacterial hand-wash types, cleaningbars, car or carpet shampoos, bathroom cleaners including toilet bowlcleaners; and metal cleaners, fabric conditioning products includingsoftening and/or freshening that may be in liquid, solid and/or dryersheet form; as well as cleaning auxiliaries such as bleach additives and“stain-stick” or pre-treat types, substrate-laden products such as dryeradded sheets, dry and wetted wipes and pads, nonwoven substrates, andsponges; as well as sprays and mists. All of such products which wereapplicable may be in standard, concentrated or even highly concentratedform even to the extent that such products may in certain aspect benon-aqueous.

As used herein, articles such as “a” and “an” when used in a claim, areunderstood to mean one or more of what is claimed or described.

As used herein, the terms “include”, “includes” and “including” aremeant to be non-limiting.

As used herein, the term “solid” includes granular, powder, bar andtablet product forms.

As used herein, the term “fluid” includes liquid, gel, paste and gasproduct forms.

As used herein, the term “situs” includes paper products, fabrics,garments, hard surfaces, hair and skin.

Unless otherwise noted, all component or composition levels are inreference to the active portion of that component or composition, andare exclusive of impurities, for example, residual solvents orby-products, which may be present in commercially available sources ofsuch components or compositions.

All percentages and ratios are calculated by weight unless otherwiseindicated. All percentages and ratios are calculated based on the totalcomposition unless otherwise indicated. It should be understood thatevery maximum numerical limitation given throughout this specificationincludes every lower numerical limitation, as if such lower numericallimitations were expressly written herein. Every minimum numericallimitation given throughout this specification will include every highernumerical limitation, as if such higher numerical limitations wereexpressly written herein. Every numerical range given throughout thisspecification will include every narrower numerical range that fallswithin such broader numerical range, as if such narrower

Perfume Raw Materials (herein after “PRMs”)

Suitable PRMs include the PRMs listed in Table 1 below and stereoisomersthereof.

TABLE 1 Chemical Structure IUPAC Names Character description 1

(S)-2,2-dimethyl-3-(4-(prop-1-en- 2-yl)cyclohex-1-enyl)propanenitrilefloral (rose geranium), woody, citrus 2

3-cyclopropyl-2- (cyclopropylmethyl)-2- methylpropanenitrile herbal,minty, vegetable 3

1-(cyclopropylmethyl)cyclo- propanecarbonitrile intense, spicy, minty 4

(S)-3,3-dimethyl-4-(4-(prop-1-en- 2-yl)cyclohex-1-enyl)butan-2-onefloral, cedarwood 5

3,3-dimethyl-4-((S)-4-(prop-1-en- 2-yl)cyclohex-1-enyl)butan-2- (R,S)-olterpenic, floral (rose, peony) 6

(S)-2,2-dimethyl-3-(4-(prop-1-en- 2-yl)cyclohex-1-enyl)propanal floral,ozonic 7

3-cyclopropyl-2-(cyclo- propylmethyl)-2-methylpropanal herbal, minty,fruity 8

3-cyclopropyl-2-(cyclopro- pylmethyl)-2-methylpropan-1-ol spicy, eugenol9

(S)-2,2-dimethyl-3-(4-(prop-1-en- 2-yl)cyclohex-1-enyl)propan-1-olfloral (whitefloral), terpenic 10

(R,S)-2,2-di(cyclohex-2- enyl)propanenitrile mint (menthone), floral(geranium) 11

(R,S)-2,2-di(cyclohex-2- enyl)acetonitrile minty, herbal 12

1-cyclopropyl-2-(cyclopropylme- thyl)-2,4-(R,S)-dimethylhexan-3- onegreen, vegetable, medicinal, intense 13

1-(1-(cyclopropyl- methyl)cyclopropyl)ethanone minty, fresh, intense 14

1-(1-(cyclopropylmethyl)- cyclopropyl)pentan-1-one spicy (celery) 15

2-methyl-2-((1R,S)(5R)-2-methyl- (prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile fresh, green (agrestic), herbal (chamomile) 16

1-(1-(cyclopropylmethyl)- cyclopropyl)pentan-1-(R,S)ol green, earthy 17

2-methyl-2-((1,R,S)(5R)-2-methyl- 5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal fresh, herbal, sulfury, truffle 18

3-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2- yl)propanenitrilewoody, pine, intense 19

(2R,S)-3-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile woody, ionone 20

1-(((1R,5S)-6,6-dimethyl- bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile pine, terpenic 21

2-methyl-2-((1,R,S)(5R)-2-methyl- 5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol floral (lily), minty 22

2-allyl-2-methylpent-4-enenitrile herbal, geranium, minty, green 23

4-allyl-4-methylnon-1-en-5-one fruity, green, herbal 24

4-allyl-4-methylnon-1-en-5-(R,S)- ol floral, herbal, baby lotion 25

iso-butyl 2,5-dimethylhex-4-enoate floral, fruity 26

7-cyclopentylideneheptan-2-one green, metallic 27

8-cyclopentylideneoctan-3-one green, vegetable 28

(E/Z)-11-methyldodec-8-en-3-one (9:1-E:Z) floral, fruity, waxy 29

(E/Z)-10-methylundec-7-en-2-one (9:1-E:Z) fruity, herbal, parsley 30

(E/Z)-10-methylundec-7-en-2- (R,S)-ol (9:1-E:Z) green, aromatic, herbal,plastic 31

propyl 7-methyloct-6-enoate fruity, floral, clean linen 32

methyl 7-methyloct-6-enoate fruity, fresh, clean, cucumber green 33

ethyl 7-methyloct-6-enoate fruity (citrus, pineapple), fresh 34

1,5,5-trimethyl-3(R,S)-(3- methylbut-2-enyloxy)cyclohex-1- ene green,herbal, terpenic 35

(E,Z)-3-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile woody, spicy, iris 36

(E,Z)(R,S)-5-(4-methylcyclohex-3- enyl)hex-2-enenitrile citrus, green,fresh, intense 37

methyl 9-methyldec-6-enoate waxy, fruity, herbal 38

4-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2- yl)butanenitrileleathery, cedar wood 39

3-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2- yl)propanal mussel,oyster, ozonic 40

4-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2- yl)butanal aldehydic,floral, physalis 41

4-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile terpenic, pine, clean 42

4-((1R,5S)-6,6- dimethylbicyclo[3.1.1]hept-2-en-2- yl)-2-methylbutanalwoody, floral 43

((1R,2R,4R,6S)-7,7- dimethyltricyclo[4.1.1.0^(2,4)]octan-2- yl)methanolwoody, terpenic 44

(1R,2R,4R,6S)-2-(methoxymethyl)- 7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane wood dust, sulphuric 45

1-(3-methylbut-2-en-1- yl)cyclopropanecarbaldehyde minty, herbal 46

2-(1-(3-methylbut-2-en-1- yl)cyclopropyl)-1,3-dioxane herbal(chamomile), aromatic, cigar 47

2-(1-(3-methylbut-2-en-1- yl)cyclopropyl)-1,3-dioxolane aromatic,herbal, fennel 48

2,2,6-trimethylhept-5-enenitrile herbal, vegetable, sharp 49

3,3,7-trimethyloct-6-en-2-one citrus, fruity, clean 50

1-(4-methylpent-3-en-1- yl)cyclobutanecarbonitrile spicy, vegetable,mushroom 51

3,3,7-trimethyloct-6-en-2-(R,S)-ol citrus, lilac, clean 52

1-(1-(4-methylpent-3-en-1- yl)cyclobutyl)ethanone fruity (cassis), woody53

1-(4-methylpent-3-en-1- yl)cyclobutanecarbaldehyde green, hay, floral 54

1-(R,S)-(1-(4-methylpent-3-en-1- yl)cyclobutyl)ethanol solventy (glue),floral (jasmin) 55

7-(R,S)-methoxy-2,6,6-trimethyloct- 2-ene herbal, mango skin 56

1-(4-methylpent-3-en-1- yl)cyclopropanecarbonitrile minty, spicy,coumarin 57

1-(1-(4-methylpent-3-en-1- yl)cyclopropyl)ethanone grapefruit, woody 58

1-(1-(4-methylpent-3-en-1- yl)cyclopropyl)pentan-1-one Green, ivy leaves59

1-(R,S)-(1-(4-methylpent-3-en-1- yl)cyclopropyl)ethanol floral rose(peony) 60

8-methylnon-7-en-2-one clean linen, fruity 61

2,6-dimethyl-2-(4-methylpent-3-en- 1-yl)hept-5-enenitrile floral(geranium, violet) 62

6-methylhept-5-enenitrile citrus, spice nitrile 63

2-(R,S),6-dimethylhept-5-enenitrile herbal, minty 64

2,6-dimethyl-2-(4-methylpent-3-en- 1-yl)hept-5-enal ozonic (mussel),fresh 65

2-(R,S),6-dimethyl-2-(3-methylbut- 2-en-1-yl)hept-5-enenitrile floral,herbal, clean 66

2-(R,S)-allyl-2,5-dimethylhex-4- enenitrile floral (violet), cucumber,lavender 67

3-(R,S)-allyl-3,6-dimethylhept-5-en- 2-one herbal (lavender), aromatic68

3-allyl-3,6-dimethylhept-5-en-2-ol humus, earthy 69

2-(R,S)-allyl-2,5-dimethylhex-4- enal floral, tea, liquorice 70

3-ethoxy-4-hydroxybenzonitrile sweet, vanilla-like 71

1-(3-ethoxy-4- hydroxyphenyl)ethanone vanillin, phenolic 72

2-ethoxy-4-(1-(R,S)- hydroxyethyl)phenol vanillin, phenolic 73

(E)-1-(2,4,4-trimethyl-7- oxabicyclo[4.1.0]heptan-3-yl)but-2- en-1-onediffusive 74

(E)-1-(5-hydroxy-4-methoxy-2,2,6- trimethylcyclohexyl)but-2-en-1-onefruity, rum, jam 75

2-ethoxy-4-(4-(R,S)-methyl-1,3- (R,S)-dioxan-2-yl)phenol sweet, woody,phenolic 76

4-(5,5-dimethyl-1,3-dioxan-2-yl)-2- ethoxyphenol sweet, chemical,vanilla 77

4-(4,4-dimethyl-1,3-(R,S)-dioxan- 2-yl)-2-ethoxyphenol Sweet, phenolic,balsamic 78

2-ethoxy-4-(4-(R,S)-ethyl-1,3- (R,S)-dioxolan-2-yl)phenol sweet,phenolic, spicy 79

2-ethoxy-4-(4-(R,S)-methyl-1,3- (R,S)-dioxolan-2-yl)phenol sweet,balsamic 80

4-(4,5-(R,S)-dimethyl-1,3-dioxolan- 2-yl)-2-ethoxyphenol sweet, balsamic81

4-(4-(R,S)-(tert-butyl)-1,3-(R,S)- dioxolan-2-yl)-2-ethoxyphenol woody,spicy, sweet 82

4-(1,3-dioxolan-2-yl)-2- ethoxyphenol sweet, woody, smoked ham 83

4-(1,3-dioxan-2-yl)-2-ethoxyphenol woody (guaiac), sweet, spicy 84

3-butoxy-4-hydroxybenzaldehyde spicy, sweet 85

2-ethoxy-4-(1,3-(R,S)-oxathiolan-2- yl)phenol sulphuric, grapefruit,mercaptan like 86

4-(4-(R,S)-butyl-1,3-(R,S)- dioxolan-2-yl)-2-ethoxyphenol floral(chrysant), sweet 87

4-hydroxy-3- (pentyloxy)benzaldehyde horsy, sweet, spicy 88

3-ethoxy-4-methoxybenzaldehyde sweet (vanilla-tonka), balsamic 89

3-ethoxy-4-methoxybenzonitrile sweet, costus 90

2-(3-ethoxy-4-methoxyphenyl)-4- methyl-1,3-(R,S)-dioxolane sweet, spicy91

2-(3-ethoxy-4-methoxyphenyl)-4,5- (R,S)-dimethyl-1,3-dioxolane sweet 92

(E)-1-(5-hydroxy-2,2,6- trimethylcyclohex-3-en-1-yl)but-2- en-1-onefruity, floral 93

2-(R,S)-isopropyl-2,5-dimethylhex- 4-enenitrile woody, herbal, intense94

2-(R,S)-isopropyl-2,6-dimethylhept- 5-enenitrile floral, ozonic(metallic)

The PRMs disclosed in Table 1 above (a.k.a., molecules—as referred to inthe Examples section) may provide one or more of the following benefitsat levels that Applicants believe are unexpected in view of PRMs ingeneral: neat product odor; wet fabric odor when applied to a fabric;dry fabric odor when applied to a fabric; reduced leakage from anencapsulate, including an encapsulate such as a perfume microcapsule;increased head space versus neat oil in certain perfume deliverytechnologies; odor when used in a matrix perfume delivery that isapplied to a package; neat product odor when applied to a cleaningand/or treatment composition; fine fragrance composition odor when usedin a fine fragrance; dry hair odor when a composition comprising such aPRM is applied to hair; PRM bloom from a solution comprising such a PRM;and new PRM character when applied to a situs. Confirmation of suchbenefits can be obtained by applying standard test methodologiesdetailed herein. The PRMs and stereoisomers of such PRMs disclosed inTable 1 above can be made in accordance with the teachings detailed inthe present specification.

In one aspect, PRMs disclosed herein may have the structure of Table 1Nos. 1-94. More specifically, PRMs disclosed herein may have thestructure of Table 1 Nos. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 12, 13, 14, 15,16, 18, 19, 20, 23, 24, 25, 26, 27, 28, 29, 30, 31, 34, 36, 41, 42, 44,46, 47, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 61, 64, 65, 66, 67, 68,69, 71, 72, 73, 74, 77, 78, 81, 85, 86, 90, 91, 93, 94, andstereoisomers thereof.

In another aspect, the PRMs disclosed in Table 1 and stereoisomersthereof are suitable for use, as defined by the present specification,in consumer products at levels, based on total consumer product weight,of from about 0.0001% to about 25%, from about 0.0005% to about 10%,from about 0.001% to about 5%, from about 0.005% to about 2.5%, or evenfrom 0.01% to about 1%. Such PRMs and stereoisomers thereof may be usedin various combinations in the aforementioned consumer products. In oneaspect, a consumer product may comprise one or more PRMs selected fromTable 1 Nos. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17,18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35,36, 37, 38, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 60, 62, 63, 64, 65,66, 67, 68, 69, 71, 72, 73, 74, 75, 77, 78, 81, 82, 83, 85, 86, 87, 89,90, 91, 92, 93, 94 and stereoisomers thereof.

In another aspect, the PRMs disclosed in Table 1 and stereoisomersthereof are suitable for use, as defined by the present specification,in cleaning and/or treatment compositions at levels, based on totalcleaning and treatment products weight of from about 0.0001% to about25%, from about 0.0005% to about 10%, from about 0.001% to about 5%,from about 0.005% to about 2.5%, or even from 0.01% to about 1%. SuchPRMs and stereoisomers thereof may be used in various combinations inthe aforementioned cleaning and treatment compositions. In one aspect, acleaning and/or treatment composition may comprise one or more PRMsselected from Table 1 Nos. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13,14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31,32, 33, 34, 35, 36, 37, 38, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 60,62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79,80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92, 93, 94 andstereoisomers thereof.

In another aspect, the PRMs disclosed in Table 1 and stereoisomersthereof are suitable for use, as defined by the present specification,in fabric and/or hard surface cleaning and/or treatment compositions atlevels, based on total fabric and/or hard surface cleaning and/ortreatment composition weight of from about 0.00001% to about 25%, from0.00005% to about 10%, from 0.0001% to about 5%, from 0.0005% to about1.0%, or even from 0.001% to about 0.5%. Such PRMs and stereoisomersthereof may be used in various combinations in the aforementioned fabricand/or hard surface cleaning and/or treatment compositions. In oneaspect, a fabric and/or hard surface cleaning and/or treatmentcomposition may comprise one or more PRMs selected from Table 1 Nos. 1,2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21,22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39,40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 60, 62, 63, 64, 65, 66, 67, 68,69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86,87, 88, 89, 90, 91, 92, 93, 94 and stereoisomers thereof.

In another aspect, a detergent that may comprise the same level of thePRMs as disclosed for the aforementioned fabric and hard surfacecleaning and/or treatment compositions is disclosed. In one aspect, adetergent may comprise one or more PRMs selected from Table 1 Nos. 1, 2,3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22,23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 40, 41,42, 43, 44, 45, 46, 47, 48, 49, 60, 62, 63, 64, 65, 66, 67, 68, 69, 70,71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88,89, 90, 91, 92, 93, 94 and stereoisomers thereof.

In another aspect, the PRMs disclosed in Table 1 and stereoisomersthereof are suitable for use in highly compacted consumer products,including highly compacted fabric and hard surface cleaning and/ortreatment compositions. For example, the PRMs disclosed in Table 1 andstereoisomers thereof may be employed in solid or fluid highly compacteddetergents at levels of from about 0.00001% to about 25%, from 0.00005%to about 10%, from 0.0001% to about 5%, from 0.0005% to about 1.0%, oreven from 0.001% to about 0.5%, based on total composition weight. SuchPRMs and stereoisomers thereof may be used in various combinations inthe aforementioned highly compacted detergent compositions. Such highlycompact detergents typically comprise a higher than normal percentage ofactive ingredients. In one aspect, a highly compacted detergent maycomprise one or more PRMs selected from Table 1 Nos. 1-94 andstereoisomers thereof. More specifically, a highly compacted detergentmay comprise one or more PRMs selected from Table 1 Nos. 1, 2, 3, 4, 5,6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24,25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 40, 41, 42, 43,44, 45, 46, 47, 48, 49, 60, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72,73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90,91, 92, 93, 94 and stereoisomers thereof.

Perfume Delivery Systems

Certain perfume delivery systems, methods of making certain perfumedelivery systems and the uses of such perfume delivery systems aredisclosed in USPA 20070275866 A1. Such perfume delivery systems include:

I. Polymer Assisted Delivery (PAD):

This perfume delivery technology uses polymeric materials to deliverperfume materials. Classical coacervation, water soluble or partlysoluble to insoluble charged or neutral polymers, liquid crystals, hotmelts, hydrogels, perfumed plastics, microcapsules, nano- andmicro-latexes, polymeric film formers, and polymeric absorbents,polymeric adsorbents, etc. are some examples. PAD includes but is notlimited to:

a.) Matrix Systems:

The fragrance is dissolved or dispersed in a polymer matrix or particle.Perfumes, for example, may be 1) dispersed into the polymer prior toformulating into the product or 2) added separately from the polymerduring or after formulation of the product. Diffusion of perfume fromthe polymer is a common trigger that allows or increases the rate ofperfume release from a polymeric matrix system that is deposited orapplied to the desired surface (situs), although many other triggers areknow that may control perfume release. Absorption and/or adsorption intoor onto polymeric particles, films, solutions, and the like are aspectsof this technology. Nano- or micro-particles composed of organicmaterials (e.g., latexes) are examples. Suitable particles include awide range of materials including, but not limited to polyacetal,polyacrylate, polyacrylic, polyacrylonitrile, polyamide,polyaryletherketone, polybutadiene, polybutylene, polybutyleneterephthalate, polychloroprene, poly ethylene, polyethyleneterephthalate, polycyclohexylene dimethylene terephthalate,polycarbonate, polychloroprene, polyhydroxyalkanoate, polyketone,polyester, polyethylene, polyetherimide, polyethersulfone,polyethylenechlorinates, polyimide, polyisoprene, polylactic acid,polymethylpentene, polyphenylene oxide, polyphenylene sulfide,polyphthalamide, polypropylene, polystyrene, polysulfone, polyvinylacetate, polyvinyl chloride, as well as polymers or copolymers based onacrylonitrile-butadiene, cellulose acetate, ethylene-vinyl acetate,ethylene vinyl alcohol, styrene-butadiene, vinyl acetate-ethylene, andmixtures thereof.

“Standard” systems refer to those that are “pre-loaded” with the intentof keeping the pre-loaded perfume associated with the polymer until themoment or moments of perfume release. Such polymers may also suppressthe neat product odor and provide a bloom and/or longevity benefitdepending on the rate of perfume release. One challenge with suchsystems is to achieve the ideal balance between 1) in-product stability(keeping perfume inside carrier until you need it) and 2) timely release(during use or from dry situs). Achieving such stability is particularlyimportant during in-product storage and product aging. This challenge isparticularly apparent for aqueous-based, surfactant-containing products,such as heavy duty liquid laundry detergents. Many “Standard” matrixsystems available effectively become “Equilibrium” systems whenformulated into aqueous-based products. One may select an “Equilibrium”system or a Reservoir system, which has acceptable in-product diffusionstability and available triggers for release (e.g., friction).“Equilibrium” systems are those in which the perfume and polymer may beadded separately to the product, and the equilibrium interaction betweenperfume and polymer leads to a benefit at one or more consumer touchpoints (versus a free perfume control that has no polymer-assisteddelivery technology). The polymer may also be pre-loaded with perfume;however, part or all of the perfume may diffuse during in-productstorage reaching an equilibrium that includes having desired perfume rawmaterials (PRMs) associated with the polymer. The polymer then carriesthe perfume to the surface, and release is typically via perfumediffusion. The use of such equilibrium system polymers has the potentialto decrease the neat product odor intensity of the neat product (usuallymore so in the case of pre-loaded standard system). Deposition of suchpolymers may serve to “flatten” the release profile and provideincreased longevity. As indicated above, such longevity would beachieved by suppressing the initial intensity and may enable theformulator to use more high impact or low odor detection threshold (ODT)or low Kovats Index (KI) PRMs to achieve FMOT benefits without initialintensity that is too strong or distorted. It is important that perfumerelease occurs within the time frame of the application to impact thedesired consumer touch point or touch points. Suitable micro-particlesand micro-latexes as well as methods of making same may be found in USPA20050003980 A1. Matrix systems also include hot melt adhesives andperfume plastics. In addition, hydrophobically modified polysaccharidesmay be formulated into the perfumed product to increase perfumedeposition and/or modify perfume release. All such matrix systems,including for example polysaccarides and nanolatexes may be combinedwith other PDTs, including other PAD systems such as PAD reservoirsystems in the form of a perfume microcapsule (PMC). Polymer AssistedDelivery (PAD) matrix systems may include those described in thefollowing references: US Patent Applications 20040110648 A1; 20040092414A1; 20040091445 A1 and 20040087476 A1; and U.S. Pat. Nos. 6,531,444;6,024,943; 6,042,792; 6,051,540; 4,540,721 and 4,973,422. Silicones arealso examples of polymers that may be used as PDT, and can provideperfume benefits in a manner similar to the polymer-assisted delivery“matrix system”. Such a PDT is referred to as silicone-assisted delivery(SAD). One may pre-load silicones with perfume, or use them as anequilibrium system as described for PAD. Suitable silicones as well asmaking same may be found in WO 2005102261; USPA 20050124530A1; USPA20050143282A1; and WO 2003015736. Functionalized silicones may also beused as described in USPA 2006003913 A1. Examples of silicones includepolydimethylsiloxane and polyalkyldimethylsiloxanes. Other examplesinclude those with amine functionality, which may be used to providebenefits associated with amine-assisted delivery (AAD) and/orpolymer-assisted delivery (PAD) and/or amine-reaction products (ARP).Other such examples may be found in U.S. Pat. No. 4,911,852; USPA20040058845 A1; USPA 20040092425 A1 and USPA 20050003980 A1.

-   -   b.) Reservoir Systems: Reservoir systems are also known as a        core-shell type technology, or one in which the fragrance is        surrounded by a perfume release controlling membrane, which may        serve as a protective shell. The material inside the        microcapsule is referred to as the core, internal phase, or        fill, whereas the wall is sometimes called a shell, coating, or        membrane. Microparticles or pressure sensitive capsules or        microcapsules are examples of this technology. Microcapsules of        the current invention are formed by a variety of procedures that        include, but are not limited to, coating, extrusion,        spray-drying, interfacial, in-situ and matrix polymerization.        The possible shell materials vary widely in their stability        toward water. Among the most stable are polyoxymethyleneurea        (PMU)-based materials, which may hold certain PRMs for even long        periods of time in aqueous solution (or product). Such systems        include but are not limited to urea-formaldehyde and/or        melamine-formaldehyde. Stable shell materials include        polyacrylate-based materials obtained as reaction product of an        oil soluble or dispersible amine with a multifunctional acrylate        or methacrylate monomer or oligomer, an oil soluble acid and an        initiator, in presence of an anionic emulsifier comprising a        water soluble or water dispersible acrylic acid alkyl acid        copolymer, an alkali or alkali salt. Gelatin-based microcapsules        may be prepared so that they dissolve quickly or slowly in        water, depending for example on the degree of cross-linking.        Many other capsule wall materials are available and vary in the        degree of perfume diffusion stability observed. Without wishing        to be bound by theory, the rate of release of perfume from a        capsule, for example, once deposited on a surface is typically        in reverse order of in-product perfume diffusion stability. As        such, urea-formaldehyde and melamine-formaldehyde microcapsules        for example, typically require a release mechanism other than,        or in addition to, diffusion for release, such as mechanical        force (e.g., friction, pressure, shear stress) that serves to        break the capsule and increase the rate of perfume (fragrance)        release. Other triggers include melting, dissolution, hydrolysis        or other chemical reaction, electromagnetic radiation, and the        like. The use of pre-loaded microcapsules requires the proper        ratio of in-product stability and in-use and/or on-surface        (on-situs) release, as well as proper selection of PRMs.        Microcapsules that are based on urea-formaldehyde and/or        melamine-formaldehyde are relatively stable, especially in near        neutral aqueous-based solutions. These materials may require a        friction trigger which may not be applicable to all product        applications. Other microcapsule materials (e.g., gelatin) may        be unstable in aqueous-based products and may even provide        reduced benefit (versus free perfume control) when in-product        aged. Scratch and sniff technologies are yet another example of        PAD. Perfume microcapsules (PMC) may include those described in        the following references: US Patent Applications: 20030125222        A1; 2003215417 A1; 2003216488 A1; 2003158344 A1; 2003165692 A1;        2004071742 A1; 2004071746 A1; 2004072719 A1; 2004072720 A1;        20060039934 A1; 2003203829 A1; 2003195133 A1; 2004087477 A1;        20040106536 A1; and U.S. Pat. Nos. 6,645,479 B1; 6,200,949 B1;        4,882,220; 4,917,920; 4,514,461; 6,106,875 and 4,234,627,        3,594,328 and US RE 32713, PCT Patent Application: WO 2009134234        A1, WO 2006127454 A2, WO 2010079466 A2, WO 2010079467 A2, WO        2010079468 A2, WO 2010084480 A2.

II. Molecule-Assisted Delivery (MAD):

Non-polymer materials or molecules may also serve to improve thedelivery of perfume. Without wishing to be bound by theory, perfume maynon-covalently interact with organic materials, resulting in altereddeposition and/or release. Non-limiting examples of such organicmaterials include but are not limited to hydrophobic materials such asorganic oils, waxes, mineral oils, petrolatum, fatty acids or esters,sugars, surfactants, liposomes and even other perfume raw material(perfume oils), as well as natural oils, including body and/or othersoils. Perfume fixatives are yet another example. In one aspect,non-polymeric materials or molecules have a CLogP greater than about 2.Molecule-Assisted Delivery (MAD) may also include those described inU.S. Pat. No. 7,119,060 and U.S. Pat. No. 5,506,201.

III. Fiber-Assisted Delivery (FAD):

The choice or use of a situs itself may serve to improve the delivery ofperfume. In fact, the situs itself may be a perfume delivery technology.For example, different fabric types such as cotton or polyester willhave different properties with respect to ability to attract and/orretain and/or release perfume. The amount of perfume deposited on or infibers may be altered by the choice of fiber, and also by the history ortreatment of the fiber, as well as by any fiber coatings or treatments.Fibers may be woven and non-woven as well as natural or synthetic.Natural fibers include those produced by plants, animals, and geologicalprocesses, and include but are not limited to cellulose materials suchas cotton, linen, hemp jute, flax, ramie, and sisal, and fibers used tomanufacture paper and cloth. Fiber-Assisted Delivery may consist of theuse of wood fiber, such as thermomechanical pulp and bleached orunbleached kraft or sulfite pulps. Animal fibers consist largely ofparticular proteins, such as silk, sinew, catgut and hair (includingwool). Polymer fibers based on synthetic chemicals include but are notlimited to polyamide nylon, PET or PBT polyester, phenol-formaldehyde(PF), polyvinyl alcohol fiber (PVOH), polyvinyl chloride fiber (PVC),polyolefins (PP and PE), and acrylic polymers. All such fibers may bepre-loaded with a perfume, and then added to a product that may or maynot contain free perfume and/or one or more perfume deliverytechnologies. In one aspect, the fibers may be added to a product priorto being loaded with a perfume, and then loaded with a perfume by addinga perfume that may diffuse into the fiber, to the product. Withoutwishing to be bound by theory, the perfume may absorb onto or beadsorbed into the fiber, for example, during product storage, and thenbe released at one or more moments of truth or consumer touch points.

IV. Amine Assisted Delivery (AAD):

The amine-assisted delivery technology approach utilizes materials thatcontain an amine group to increase perfume deposition or modify perfumerelease during product use. There is no requirement in this approach topre-complex or pre-react the perfume raw material(s) and amine prior toaddition to the product. In one aspect, amine-containing AAD materialssuitable for use herein may be non-aromatic; for example,polyalkylimine, such as polyethyleneimine (PEI), or polyvinylamine(PVAm), or aromatic, for example, anthranilates. Such materials may alsobe polymeric or non-polymeric. In one aspect, such materials contain atleast one primary amine. This technology will allow increased longevityand controlled release also of low ODT perfume notes (e.g., aldehydes,ketones, enones) via amine functionality, and delivery of other PRMs,without being bound by theory, via polymer-assisted delivery forpolymeric amines. Without technology, volatile top notes can be lost tooquickly, leaving a higher ratio of middle and base notes to top notes.The use of a polymeric amine allows higher levels of top notes and otherPRMS to be used to obtain freshness longevity without causing neatproduct odor to be more intense than desired, or allows top notes andother PRMs to be used more efficiently. In one aspect, AAD systems areeffective at delivering PRMs at pH greater than about neutral. Withoutwishing to be bound by theory, conditions in which more of the amines ofthe AAD system are deprotonated may result in an increased affinity ofthe deprotonated amines for PRMs such as aldehydes and ketones,including unsaturated ketones and enones such as damascone. In anotheraspect, polymeric amines are effective at delivering PRMs at pH lessthan about neutral. Without wishing to be bound by theory, conditions inwhich more of the amines of the AAD system are protonated may result ina decreased affinity of the protonated amines for PRMs such as aldehydesand ketones, and a strong affinity of the polymer framework for a broadrange of PRMs. In such an aspect, polymer-assisted delivery may bedelivering more of the perfume benefit; such systems are a subspecies ofAAD and may be referred to as Amine-Polymer-Assisted Delivery or APAD.In some cases when the APAD is employed in a composition that has a pHof less than seven, such APAD systems may also be consideredPolymer-Assisted Delivery (PAD). In yet another aspect, AAD and PADsystems may interact with other materials, such as anionic surfactantsor polymers to form coacervate and/or coacervates-like systems. Inanother aspect, a material that contains a heteroatom other thannitrogen, for example sulfur, phosphorus or selenium, may be used as analternative to amine compounds. In yet another aspect, theaforementioned alternative compounds can be used in combination withamine compounds. In yet another aspect, a single molecule may comprisean amine moiety and one or more of the alternative heteroatom moieties,for example, thiols, phosphines and selenols. Suitable AAD systems aswell as methods of making same may be found in US Patent Applications20050003980 A1; 20030199422 A1; 20030036489 A1; 20040220074 A1 and U.S.Pat. No. 6,103,678.

V. Cyclodextrin Delivery System (CD):

This technology approach uses a cyclic oligosaccharide or cyclodextrinto improve the delivery of perfume. Typically a perfume and cyclodextrin(CD) complex is formed. Such complexes may be preformed, formed in-situ,or formed on or in the situs. Without wishing to be bound by theory,loss of water may serve to shift the equilibrium toward the CD-Perfumecomplex, especially if other adjunct ingredients (e.g., surfactant) arenot present at high concentration to compete with the perfume for thecyclodextrin cavity. A bloom benefit may be achieved if water exposureor an increase in moisture content occurs at a later time point. Inaddition, cyclodextrin allows the perfume formulator increasedflexibility in selection of PRMs. Cyclodextrin may be pre-loaded withperfume or added separately from perfume to obtain the desired perfumestability, deposition or release benefit. Suitable CDs as well asmethods of making same may be found in USPA 20050003980 A1 and20060263313 A1 and U.S. Pat. Nos. 5,552,378; 3,812,011; 4,317,881;4,418,144 and 4,378,923.

VI. Starch Encapsulated Accord (SEA):

The use of a starch encapsulated accord (SEA) technology allows one tomodify the properties of the perfume, for example, by converting aliquid perfume into a solid by adding ingredients such as starch. Thebenefit includes increased perfume retention during product storage,especially under non-aqueous conditions. Upon exposure to moisture, aperfume bloom may be triggered. Benefits at other moments of truth mayalso be achieved because the starch allows the product formulator toselect PRMs or PRM concentrations that normally cannot be used withoutthe presence of SEA. Another technology example includes the use ofother organic and inorganic materials, such as silica to convert perfumefrom liquid to solid. Suitable SEAs as well as methods of making samemay be found in USPA 20050003980 A1 and U.S. Pat. No. 6,458,754 B1.

VII. Inorganic Carrier Delivery System (ZIC):

This technology relates to the use of porous zeolites or other inorganicmaterials to deliver perfumes. Perfume-loaded zeolite may be used withor without adjunct ingredients used for example to coat theperfume-loaded zeolite (PLZ) to change its perfume release propertiesduring product storage or during use or from the dry situs. Suitablezeolite and inorganic carriers as well as methods of making same may befound in USPA 20050003980 A1 and U.S. Pat. Nos. 5,858,959; 6,245,732 B1;6,048,830 and 4,539,135. Silica is another form of ZIC. Another exampleof a suitable inorganic carrier includes inorganic tubules, where theperfume or other active material is contained within the lumen of thenano- or micro-tubules. In one aspect, the perfume-loaded inorganictubule (or Perfume-Loaded Tubule or PLT) is a mineral nano- ormicro-tubule, such as halloysite or mixtures of halloysite with otherinorganic materials, including other clays. The PLT technology may alsocomprise additional ingredients on the inside and/or outside of thetubule for the purpose of improving in-product diffusion stability,deposition on the desired situs or for controlling the release rate ofthe loaded perfume. Monomeric and/or polymeric materials, includingstarch encapsulation, may be used to coat, plug, cap, or otherwiseencapsulate the PLT. Suitable PLT systems as well as methods of makingsame may be found in U.S. Pat. No. 5,651,976.

VIII. Pro-Perfume (PP):

This technology refers to perfume technologies that result from thereaction of perfume materials with other substrates or chemicals to formmaterials that have a covalent bond between one or more PRMs and one ormore carriers. The PRM is converted into a new material called a pro-PRM(i.e., pro-perfume), which then may release the original PRM uponexposure to a trigger such as water or light. Pro-perfumes may provideenhanced perfume delivery properties such as increased perfumedeposition, longevity, stability, retention, and the like. Pro-perfumesinclude those that are monomeric (non-polymeric) or polymeric, and maybe pre-formed or may be formed in-situ under equilibrium conditions,such as those that may be present during in-product storage or on thewet or dry situs. Nonlimiting examples of pro-perfumes include Michaeladducts (e.g., beta-amino ketones), aromatic or non-aromatic imines(Schiff bases), oxazolidines, beta-keto esters, and orthoesters. Anotheraspect includes compounds comprising one or more beta-oxy or beta-thiocarbonyl moieties capable of releasing a PRM, for example, an alpha,beta-unsaturated ketone, aldehyde or carboxylic ester. The typicaltrigger for perfume release is exposure to water; although othertriggers may include enzymes, heat, light, pH change, autoxidation, ashift of equilibrium, change in concentration or ionic strength andothers. For aqueous-based products, light-triggered pro-perfumes areparticularly suited. Such photo-pro-perfumes (PPPs) include but are notlimited to those that release coumarin derivatives and perfumes and/orpro-perfumes upon being triggered. The released pro-perfume may releaseone or more PRMs by means of any of the above mentioned triggers. In oneaspect, the photo-pro-perfume releases a nitrogen-based pro-perfume whenexposed to a light and/or moisture trigger. In another aspect, thenitrogen-based pro-perfume, released from the photo-pro-perfume,releases one or more PRMs selected, for example, from aldehydes, ketones(including enones) and alcohols. In still another aspect, the PPPreleases a dihydroxy coumarin derivative. The light-triggeredpro-perfume may also be an ester that releases a coumarin derivative anda perfume alcohol. In one aspect the pro-perfume is a dimethoxybenzoinderivative as described in USPA 20060020459 A1. In another aspect thepro-perfume is a 3′, 5′-dimethoxybenzoin (DMB) derivative that releasesan alcohol upon exposure to electromagnetic radiation. In yet anotheraspect, the pro-perfume releases one or more low ODT PRMs, includingtertiary alcohols such as linalool, tetrahydrolinalool, ordihydromyrcenol. Suitable pro-perfumes and methods of making same can befound in U.S. Pat. Nos. 7,018,978 B2; 6,987,084 B2; 6,956,013 B2;6,861,402 B1; 6,544,945 B1; 6,093,691; 6,277,796 B1; 6,165,953;6,316,397 B1; 6,437,150 B1; 6,479,682 B1; 6,096,918; 6,218,355 B1;6,133,228; 6,147,037; 7,109,153 B2; 7,071,151 B2; 6,987,084 B2;6,610,646 B2 and 5,958,870, as well as can be found in USPA 20050003980A1 and USPA 20060223726 A1.

a.) Amine Reaction Product (ARP):

For purposes of the present application, ARP is a subclass or species ofPP. One may also use “reactive” polymeric amines in which the aminefunctionality is pre-reacted with one or more PRMs to form an aminereaction product (ARP). Typically the reactive amines are primary and/orsecondary amines, and may be part of a polymer or a monomer(non-polymer). Such ARPs may also be mixed with additional PRMs toprovide benefits of polymer-assisted delivery and/or amine-assisteddelivery. Nonlimiting examples of polymeric amines include polymersbased on polyalkylimines, such as polyethyleneimine (PEI), orpolyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric)amines include hydroxyl amines, such as 2-aminoethanol and its alkylsubstituted derivatives, and aromatic amines such as anthranilates. TheARPs may be premixed with perfume or added separately in leave-on orrinse-off applications. In another aspect, a material that contains aheteroatom other than nitrogen, for example oxygen, sulfur, phosphorusor selenium, may be used as an alternative to amine compounds. In yetanother aspect, the aforementioned alternative compounds can be used incombination with amine compounds. In yet another aspect, a singlemolecule may comprise an amine moiety and one or more of the alternativeheteroatom moieties, for example, thiols, phosphines and selenols. Thebenefit may include improved delivery of perfume as well as controlledperfume release. Suitable ARPs as well as methods of making same can befound in USPA 20050003980 A1 and U.S. Pat. No. 6,413,920 B1.

In one aspect, the PRMs disclosed in Table 1 and stereoisomers thereofare suitable for use in perfume delivery systems at levels, based ontotal perfume delivery system weight, of from 0.001% to about 50%, from0.005% to 30%, from 0.01% to about 10%, from 0.025% to about 5%, or evenfrom 0.025% to about 1%.

In another aspect, the perfume delivery systems disclosed herein aresuitable for use in consumer products, cleaning and treatmentcompositions, fabric and hard surface cleaning and/or treatmentcompositions, detergents, and highly compacted consumer products,including highly compacted fabric and hard surface cleaning and/ortreatment compositions (e.g., solid or fluid highly compacteddetergents) at levels, based on total consumer product weight, fromabout 0.001% to about 20%, from about 0.01% to about 10%, from about0.05% to about 5%, from about 0.1% to about 0.5%.

In another aspect, the amount of PRMs from Table 1 present in theperfume delivery systems, based on the total microcapsule and/ornanocapsule (Polymer Assisted Delivery (PAD) Reservoir System) weight,may be from about 0.1% to about 99%, from 25% to about 95%, from 30 toabout 90%, from 45% to about 90%, or from 65% to about 90%. In oneaspect, microcapsules and/or nanocapsules may comprise one or more PRMsselected from Table 1 Nos. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13,14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31,32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49,60, 62, 63, 64, 65, 66, 67, 68, 69, 71, 72; stereoisomers of Table 1Nos. 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19,20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37,38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 60, 62, 63, 64, 65, 66,67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84,85, 86, 87, 88, 89, 90, 91, 92, 93, 94; and mixtures thereof.

PRM Nos. 4, 12, 13, 14, 23, 26, 27, 28, 29, 49, 52, 57, 58, 60, 67, 71,73, 74 and 92 are ketones. PRM Nos. 6, 7, 17, 39, 40, 42, 45, 53, 64,69, 84, 87 and 88 are aldehydes. PRM Nos. 5, 8, 9, 16, 21, 24, 30, 43,51, 54, 59, 68, 72, 75, 76, 77, 78, 79, 80, 81, 82, 83, 85, and 86 arealcohols. PRM Nos. 25, 31, 32, 33, 37, 44 and 55 are esters. PRM Nos. 1,2, 3, 10, 11, 15, 18, 19, 20, 22, 35, 36, 38, 41, 48, 50, 56, 61, 62,63, 65, 66, 70, 89, 93 and 94 are nitriles. PRM No. 34 is an ether. PRMNo. 46 is an dioxane. PRM Nos. 47, 90 and 91 are dioxolanes.

In one aspect, the amount of total perfume based on total weight ofstarch encapsulates and starch agglomerates (Starch Encapsulated Accord(SEA)) ranges from 0.1% to about 99%, from 25% to about 95%, from 30 toabout 90%, from 45% to about 90%, from 65% to about 90%. In one aspect,the PRMs disclosed in Table 1 and stereoisomers thereof are suitable foruse in such starch encapsulates and starch agglomerates. Such PRMs andstereoisomers thereof may be used in combination in such starchencapsulates and starch agglomerates.

In another aspect, the amount of total perfume based on total weight of[cyclodextrin-perfume] complexes (Cyclodextrin (CD)) ranges from 0.1% toabout 99%, from 2.5% to about 75%, from 5% to about 60%, from 5% toabout 50%, from 5% to about 25%. In one aspect, the PRMs disclosed inTable 1 and stereoisomers thereof are suitable for use in such[cyclodextrin-perfume] complexes. Such PRMs and stereoisomers thereofmay be used in combination in such [cyclodextrin-perfume] complexes.

In another aspect, the amount of total perfume based on total weight ofPolymer Assisted Delivery (PAD) Matrix Systems (including Silicones)ranges from 0.1% to about 99%, from 2.5% to about 75%, from 5% to about60%, from 5% to about 50%, from 5% to about 25%. In one aspect, theamount of total perfume based on total weight of a hot melt perfumedelivery system/perfume loaded plastic Matrix System and ranges from 1%to about 99%, from 2.5% to about 75%, from 5% to about 60%, from 5% toabout 50%, from 10% to about 50%. In one aspect, the PRMs disclosed inTable 1 and stereoisomers thereof are suitable for use in such PolymerAssisted Delivery (PAD) Matrix Systems, including hot melt perfumedelivery system/perfume loaded plastic Matrix Systems. Such PRMs andstereoisomers thereof may be used in various combinations in suchPolymer Assisted Delivery (PAD) Matrix Systems (including hot meltperfume delivery system/perfume loaded plastic Matrix Systems).

In one aspect, the amount of total perfume based on total weight ofAmine Assisted Delivery (AAD) (including Aminosilicones) ranges from 1%to about 99%, from 2.5% to about 75%, from 5% to about 60%, from 5% toabout 50%, from 5% to about 25%. In one aspect, the PRMs disclosed inTable 1 and stereoisomers thereof are suitable for use in such AmineAssisted Delivery (AAD) systems. Such PRMs and stereoisomers thereof maybe used in various combinations in such Amine Assisted Delivery (AAD)systems. In one aspect, an Amine Assisted Delivery (AAD) system maycomprise one or more PRMs selected from Table 1 Nos. 1, 2, 3, 4, 5, 6,7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25,26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43,44, 45, 46, 47, 48, 49, 60, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72,73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90,91, 92, 93, 94; stereoisomers of Table 1 Nos. 1, 2, 3, 4, 5, 6, 7, 8, 9,10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27,28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45,46, 47, 48, 49, 60, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74,75, 76, 77, 78, 79, 80, 81, 82, 83, 84, 85, 86, 87, 88, 89, 90, 91, 92,93, 94; and mixtures thereof.

PRM Nos. 4, 12, 13, 14, 23, 26, 27, 28, 29, 49, 52, 57, 58, 60, 67, 71,73, 74 and 92 are ketones. PRM Nos. 6, 7, 17, 39, 40, 42, 45, 53, 64,69, 84, 87 and 88 are aldehydes. PRM Nos. 5, 8, 9, 16, 21, 24, 30, 43,51, 54, 59, 68, 72, 75, 76, 77, 78, 79, 80, 81, 82, 83, 85, and 86 arealcohols. PRM Nos. 25, 31, 32, 33, 37, 44 and 55 are esters. PRM Nos. 1,2, 3, 10, 11, 15, 18, 19, 20, 22, 35, 36, 38, 41, 48, 50, 56, 61, 62,63, 65, 66, 70, 89, 93 and 94 are nitriles. PRM No. 34 is an ether. PRMNo. 46 is an dioxane. PRM Nos. 47, 90 and 91 are dioxolanes.

In one aspect, a Pro-Perfume (PP) Amine Reaction Product (ARP) systemmay comprise one or more PRMs selected from Table 1 Nos. 35, 36. SuchPRMs are nitriles In one aspect, a Pro-Perfume (PP) Amine ReactionProduct (ARP) system may comprise one or more PRMs selected from Table 1Nos. 4, 12, 13, 14, 23, 26, 27, 28, 29, 49, 52, 57, 58, 60, 67, 71, 73,74 and 92. Such PRMs are ketones. In one aspect, a Pro-Perfume (PP)Amine Reaction Product (ARP) system may comprise one or more PRMsselected from Table 1 Nos. 6, 7, 17, 39, 40, 42, 53, 64, 84, 87, 88.Such PRMs are aldehydes. In one aspect, the amount of total perfumebased on total weight of Pro-Perfume (PP) Amine Reaction Product (ARP)system ranges from 0.1% to about 99%, from about 1% to about 99%, from5% to about 90%, from 10% to about 75%, from 20% to about 75%, from 25%to about 60%.

The perfume delivery technologies (a.k.a., perfume delivery systems)that are disclosed in the present specification may be used in anycombination in any type of consumer product, cleaning and/or treatmentcomposition, fabric and hard surface cleaning and/or treatmentcomposition, detergent, and/or highly compact detergent.

Perfumes

The PRMs disclosed in Table 1 may be used to formulate perfumes. Suchperfumes are combinations of PRMs that may comprise a combination ofTable 1 PRMs, or one or more Table 1 PRMs and one or more additionalPRMs. When used in a perfume, the Table 1 PRMs may be employed, based ontotal perfume weight, at levels of from about 0.01% to about 50%, fromabout 0.1% to about 15%, from about 0.1% to about 10% or even from about0.5% to about 10%. Such perfumes may be utilized in variousapplications, including being applied neat to a situs or used in aconsumer product, cleaning and/or treatment composition, fabric and hardsurface cleaning and/or treatment composition, detergent, and/or ahighly compact detergent.

Adjunct Materials

For the purposes of the present invention, the non-limiting list ofadjuncts illustrated hereinafter are suitable for use in thecompositions detailed herein (e.g., consumer products, cleaning and/ortreatment compositions, fabric and hard surface cleaning and/ortreatment compositions, detergents, and/or a highly compact detergents).Such adjunct materials may be desirably incorporated in certainembodiments of the compositions, for example to assist or enhanceperformance of the composition, for treatment of the substrate to becleaned, or to modify the aesthetics of the composition as is the casewith perfumes, colorants, dyes or the like. It is understood that suchadjuncts are in addition to the components that are supplied viaApplicants' perfumes and/or perfume systems detailed herein. The precisenature of these additional components, and levels of incorporationthereof, will depend on the physical form of the composition and thenature of the operation for which it is to be used.

Suitable adjunct materials include, but are not limited to, surfactants,builders, chelating agents, dye transfer inhibiting agents, dispersants,enzymes, and enzyme stabilizers, catalytic materials, bleach activators,polymeric dispersing agents, clay soil removal/anti-redeposition agents,brighteners, suds suppressors, dyes, additional perfume and perfumedelivery systems, structure elasticizing agents, fabric softeners,carriers, hydrotropes, processing aids and/or pigments. In addition tothe disclosure below, suitable examples of such other adjuncts andlevels of use are found in U.S. Pat. Nos. 5,576,282, 6,306,812 B1 and6,326,348 B1.

Each adjunct ingredient is not essential to Applicants' compositions.Thus, certain embodiments of Applicants' compositions may not containone or more of the following adjuncts materials: bleach activators,surfactants, builders, chelating agents, dye transfer inhibiting agents,dispersants, enzymes, and enzyme stabilizers, catalytic metal complexes,polymeric dispersing agents, clay and soil removal/anti-redepositionagents, brighteners, suds suppressors, dyes, additional perfumes andperfume delivery systems, structure elasticizing agents, fabricsofteners, carriers, hydrotropes, processing aids and/or pigments.However, when one or more adjuncts are present, such adjuncts may bepresent as detailed below:

Surfactants—The compositions according to the present invention cancomprise a surfactant or surfactant system wherein the surfactant can beselected from nonionic and/or anionic and/or cationic surfactants and/orampholytic and/or zwitterionic and/or semi-polar nonionic surfactants.The surfactant is typically present at a level of from about 0.1%, fromabout 1%, or even from about 5% by weight of the cleaning compositionsto about 99.9%, to about 80%, to about 35%, or even to about 30% byweight of the cleaning compositions.

Builders—The compositions of the present invention can comprise one ormore detergent builders or builder systems. When present, thecompositions will typically comprise at least about 1% builder, or fromabout 5% or 10% to about 80%, 50%, or even 30% by weight, of saidbuilder. Builders include, but are not limited to, the alkali metal,ammonium and alkanolammonium salts of polyphosphates, alkali metalsilicates, alkaline earth and alkali metal carbonates, aluminosilicatebuilders polycarboxylate compounds, ether hydroxypolycarboxylates,copolymers of maleic anhydride with ethylene or vinyl methyl ether,1,3,5-trihydroxybenzene-2,4,6-trisulphonic acid, andcarboxymethyl-oxysuccinic acid, the various alkali metal, ammonium andsubstituted ammonium salts of polyacetic acids such as ethylenediaminetetraacetic acid and nitrilotriacetic acid, as well as polycarboxylatessuch as mellitic acid, succinic acid, oxydisuccinic acid, polymaleicacid, benzene 1,3,5-tricarboxylic acid, carboxymethyloxysuccinic acid,and soluble salts thereof.

Chelating Agents—The compositions herein may also optionally contain oneor more copper, iron and/or manganese chelating agents. If utilized,chelating agents will generally comprise from about 0.1% by weight ofthe compositions herein to about 15%, or even from about 3.0% to about15% by weight of the compositions herein.

Dye Transfer Inhibiting Agents—The compositions of the present inventionmay also include one or more dye transfer inhibiting agents. Suitablepolymeric dye transfer inhibiting agents include, but are not limitedto, polyvinylpyrrolidone polymers, polyamine N-oxide polymers,copolymers of N-vinylpyrrolidone and N-vinylimidazole,polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof. Whenpresent in the compositions herein, the dye transfer inhibiting agentsare present at levels from about 0.0001%, from about 0.01%, from about0.05% by weight of the cleaning compositions to about 10%, about 2%, oreven about 1% by weight of the cleaning compositions.

Dispersants—The compositions of the present invention can also containdispersants. Suitable water-soluble organic materials are the homo- orco-polymeric acids or their salts, in which the polycarboxylic acid maycomprise at least two carboxyl radicals separated from each other by notmore than two carbon atoms.

Enzymes—The compositions can comprise one or more detergent enzymeswhich provide cleaning performance and/or fabric care benefits. Examplesof suitable enzymes include, but are not limited to, hemicellulases,peroxidases, proteases, cellulases, xylanases, lipases, phospholipases,esterases, cutinases, pectinases, keratanases, reductases, oxidases,phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases,pentosanases, malanases, β-glucanases, arabinosidases, hyaluronidase,chondroitinase, laccase, and amylases, or mixtures thereof. A typicalcombination is a cocktail of conventional applicable enzymes likeprotease, lipase, cutinase and/or cellulase in conjunction with amylase.

Enzyme Stabilizers—Enzymes for use in compositions, for example,detergents can be stabilized by various techniques. The enzymes employedherein can be stabilized by the presence of water-soluble sources ofcalcium and/or magnesium ions in the finished compositions that providesuch ions to the enzymes.

Catalytic Metal Complexes Applicants' compositions may include catalyticmetal complexes. One type of metal-containing bleach catalyst is acatalyst system comprising a transition metal cation of defined bleachcatalytic activity, such as copper, iron, titanium, ruthenium, tungsten,molybdenum, or manganese cations, an auxiliary metal cation havinglittle or no bleach catalytic activity, such as zinc or aluminumcations, and a sequestrate having defined stability constants for thecatalytic and auxiliary metal cations, particularlyethylenediaminetetraacetic acid, ethylenediaminetetra(methyl-enephosphonic acid) and water-soluble salts thereof. Suchcatalysts are disclosed in U.S. Pat. No. 4,430,243.

If desired, the compositions herein can be catalyzed by means of amanganese compound. Such compounds and levels of use are well known inthe art and include, for example, the manganese-based catalystsdisclosed in U.S. Pat. No. 5,576,282. Cobalt bleach catalysts usefulherein are known, and are described, for example, in U.S. Pat. Nos.5,597,936 and 5,595,967. Such cobalt catalysts are readily prepared byknown procedures, such as taught for example in U.S. Pat. Nos.5,597,936, and 5,595,967.

Compositions herein may also suitably include a transition metal complexof a macropolycyclic rigid ligand—abbreviated as “MRL”. As a practicalmatter, and not by way of limitation, the compositions and cleaningprocesses herein can be adjusted to provide on the order of at least onepart per hundred million of the benefit agent MRL species in the aqueouswashing medium, and may provide from about 0.005 ppm to about 25 ppm,from about 0.05 ppm to about 10 ppm, or even from about 0.1 ppm to about5 ppm, of the MRL in the wash liquor. Suitable transition-metals in theinstant transition-metal bleach catalyst include manganese, iron andchromium. Suitable MRL's herein are a special type of ultra-rigid ligandthat is cross-bridged such as5,12-diethyl-1,5,8,12-tetraazabicyclo[6.6.2]hexa-decane. Suitabletransition metal MRLs are readily prepared by known procedures, such astaught for example in WO 0032601, and U.S. Pat. No. 6,225,464.

Methods of Use

Some of the consumer products disclosed herein can be used to clean ortreat a situs inter alia a surface or fabric. Typically at least aportion of the situs is contacted with an embodiment of Applicants'composition, in neat form or diluted in a liquor, for example, a washliquor and then the situs may be optionally washed and/or rinsed. In oneaspect, a situs is optionally washed and/or rinsed, contacted with aparticle according to the present invention or composition comprisingsaid particle and then optionally washed and/or rinsed. For purposes ofthe present invention, washing includes but is not limited to,scrubbing, and mechanical agitation. The fabric may comprise most anyfabric capable of being laundered or treated in normal consumer useconditions. Liquors that may comprise the disclosed compositions mayhave a pH of from about 3 to about 11.5. Such compositions are typicallyemployed at concentrations of from about 500 ppm to about 15,000 ppm insolution. When the wash solvent is water, the water temperaturetypically ranges from about 5° C. to about 90° C. and, when the situscomprises a fabric, the water to fabric ratio is typically from about1:1 to about 30:1.

Test Methods

It is understood that the test methods that are disclosed in the TestMethods Section of the present application should be used to determinethe respective values of the parameters of Applicants' invention as suchinvention is described and claimed herein.

-   -   (1) ClogP

The “calculated logP” (ClogP) is determined by the fragment approach ofHansch and Leo (cf., A. Leo, in Comprehensive Medicinal Chemistry, Vol.4, C. Hansch, P. G. Sammens, J. B. Taylor, and C. A. Ramsden, Eds. P.295, Pergamon Press, 1990, incorporated herein by reference). ClogPvalues may be calculated by using the “CLOGP” program available fromDaylight Chemical Information Systems Inc. of Irvine, Calif. U.S.A.

-   -   (2) Boiling Point

Boiling point is measured by ASTM method D2887-04a, “Standard TestMethod for Boiling Range Distribution of Petroleum Fractions by GasChromatography,” ASTM International.

-   -   (3) Headspace Ratio    -   (a) Obtain a fragrance free consumer product formulation        (shampoo or leave-on conditioner).    -   (b) Obtain fragrance microcapsules whose water content has been        adjusted to achieve a perfume content of 25 wt % in the aqueous        slurry.    -   (c) Prepare Sample A by adding 2.0 grams of the fragrance        microcapsule aqueous slurry to 95 grams of the fragrance free        consumer product formulation. Then add 3.0 grams of deionized        water to balance the formulation to 100 grams. Age this        formulation for 1 week at 40 degrees Centigrade.    -   (d) Prepare Sample B by adding 0.50 grams of the neat fragrance        to 95 grams of fragrance free consumer product formulation. Then        add 4.5 grams of deionized water to balance the formulation to        100 grams. Age this formulation for 1 week at 40 degrees        Centigrade.

The Headspace Ratio for determining perfume leakage from a perfumedelivery system is defined as the headspace concentration of Sample Adivided by the headspace concentration of Sample B,

$\frac{H_{Sample\_ A}}{H_{Sample\_ B}},$

where H_(Sample) _(—) _(A) is the headspace concentration of a consumerproduct formulation Sample A, and H_(Sample) _(—) _(B) is the headspaceconcentration of a consumer product formulation Sample B.

The Headspace Ratio for determining perfume delivery efficiency from aperfume delivery system is defined as the headspace concentration ofSample B divided by the headspace concentration of Sample A,

$\frac{H_{Sample\_ B}}{H_{Sample\_ A}},$

where H_(Sample) _(—) _(A) is the headspace concentration of a consumerproduct formulation Sample A, and H_(Sample) _(—) _(B) is the headspaceconcentration of a consumer product formulation Sample B.

Solid-Phase Micro-Extraction (SPME)-Gas ChromatographyMass Spectrometryis used to measure the level of perfume raw materials in the headspaceof products. 1.0 grams of the 1 week at 40 degrees Centigrade agedsample (shampoo or conditioner) are placed into a clean 20 ml headspacevial and allowed to equilibrate for at least 2 hours at roomtemperature.

The samples are then analyzed using the MPS2-SMPE-GC-MS analysis system(GC-02001-0153, MSD-02001-0154, MPS2-02001-0155).

Apparatus:

-   1. 20 ml headspace vial-   2. Timer.-   3. Gas Chromatograph (GC): Agilent model 6890 with a CIS-4 injector    (Gerstel, Mulheim, Germany) and MPS-2 Autosampler and TDU. For SPME    analysis, we used the splitsplitless injector (not the CIS-4    injector).-   4. GC column: J&W DB-5 MS, 30 M×0.25 mm ID, 1.0 m film thickness    obtained from J&W Scientific of Folsom, Calif., USA.-   5. Carrier gas, helium, 1.5 ml/min. flow rate.-   6. The injector liner is a special SPME liner (0.75 mm ID) from    Supelco.-   7. The Detector is a model 5973 Mass Selective Detector obtained    from Agilent Technologies, Inc., Wilmington, Del., USA having a    source temperature of about 230° C., and a MS Quad temperature of    about 150° C.    Analysis procedure:    -   1. Transfer sample to proper sample tray and proceed with        SPME-GC-MS analysis.    -   2. Start sequence of sample loading and analysis. In this step,        the sample is allowed to equilibrate for at least two hours on        the auto sampler tray, then sampled directly from the tray. The        SPME fiber assembly is DVB/CAR/PDMS (5030 um, 24 ga, 1 cm        length). Sampling time is 5 minutes.    -   3. Injector temperature is at 260 C.    -   4. Then GC-MS analysis run is started. Desportion time is 5        minutes.    -   5. The following temperature program is used:        -   i) an initial temperature of about 50° C. which is held for            3 minutes,        -   ii) increase the initial temperature at a rate of about 6°            C./min until a temperature of about 250° C. is reached, then            25° C./min to 275° C., hold at about 275° C. for 4.67            minute.    -   6. Perfume compounds are identified using the MS spectral        libraries of John Wiley & Sons and the National Institute of        Standards and Technology (NIST), purchased and licensed through        Hewlett Packard.    -   7. Chromatographic peaks for specific ions are integrated using        the Chemstation software obtained from Agilent Technologies,        Inc., Wilmington, Del., USA.    -   8. The ratio for each PRM is calculated by dividing the peak        area for the perfume raw material in Sample A by the peak area        in Sample B.    -   9. Each ratio is then weighted by that perfume raw material's        weight composition in the perfume.    -   10. The Headspace Ratio is calculated as the sum of the        individual perfume raw material ratios obtained in step 9.    -   (4) Perfume leakage can also be evaluated via % liquid-liquid        extraction and gas chromatographic-mass spectrometric analysis

When determining the % perfume leakage from Perfume Microcapsules inliquid detergent, a fresh sample of liquid detergent with equal level offree perfume (without Perfume Microcapsules) must also be analyzed inparallel for reference.

1. Preparation of an Internal Standard Solution

-   -   Stock solution of tonalid: Weigh 70 mg tonalid and add 20 ml        hexane p.a.    -   Internal Standard Solution solution: Dilute 200 μl of stock        solution in 20 ml hexane p.a.    -   Mix to homogenize

2. Perfume Extraction from Liquid Detergent without PerfumeMicrocapsules (Reference)

-   -   Weigh 2 g of liquid detergent product into an extraction vessel    -   Add 2 ml of Internal Standard Solution and close vessel    -   Extract perfume by gently turning the extraction vessel        upside-down for 20 times (manually)    -   Add spoon tip of Sodium Sulphate    -   After separation of layers, immediately transfer hexane-layer        into Gas Chromatograph auto sampler-vial and cap vial    -   Inject splitless (1.50) into Gas Chromatograph injection-port    -   Run Gas Chromatographic-Mass Spectrometric analysis

3. Perfume Extraction from Liquid Detergent with Perfume Microcapsules

-   -   Weigh 2 g of liquid detergent product into an extraction vessel    -   Add 2 ml of Internal Standard Solution and close vessel    -   Extract perfume by gently turning the extraction vessel        upside-down for 20 times (manually)    -   Add spoon tip of Sodium Sulphate    -   After separation of layers, immediately transfer hexane-layer        into Gas Chromatograph auto sampler-vial and cap vial    -   Inject splitless (1.5 μl) into Gas Chromatograph injection-port    -   Run Gas Chromatographic-Mass Spectrometric analysis

4. Calculation

-   -   The perfume leakage from capsules per individual Perfume Raw        Material:

% perfume leakage=((Area Perfume Raw Material caps×Area InternalStandard Solution ref×Weight ref)/(Area Internal Standard Solutioncaps×Area Perfume Raw Material ref×Weight caps))×100

-   -   (5) Odor Detection Threshold (ODT)

Determined using a gas chromatograph. The gas chromatograph iscalibrated to determine the exact volume of material injected by thesyringe, the precise split ratio, and the hydrocarbon response using ahydrocarbon standard of known concentration and chain lengthdistribution. The air flow rate is accurately measured and, assuming theduration of human inhalation to last 12 seconds, the sampled volume iscalculated. Since the precise concentration at the detector at any pointin time is known, the mass per volume inhaled is known, and hence theconcentration of material.

For example, to determine whether a material has a threshold below 50parts per bullion, solutions are delivered to the sniff port at thecalculated concentration. A panelist sniffs the GC effluent andidentifies the retention time when odor is noticed. The average among 6panelists determines the threshold of noticeability. The necessaryamount of analyte is injected into the column to achieve a 50 parts perbillion concentration at the detector. Typical gas chromatographparameters for determining odor detection thresholds are listed below:

-   -   GC: 5890 Series II with FID detector, 7673 Autosampler    -   Column: J&W Scientific DB-1    -   Length: 30 meters, 0.25 millmeter inside diameter, 1 micrometer        film thickness    -   Method:        -   split injection: 171 split ratio        -   Autosampler: 1.13 microliters per injection        -   Column flow: 1.10 milliLiters per minute        -   Air Flow: 345 milliLiters per minute        -   Inlet Temperature: 245 degrees Centigrade        -   Detector Temperature: 285 degrees Centigrade        -   Initial Temperature=50 degrees Centigrade, 5 degrees            Centigrade per minute ramp rate, final temperature=280            degrees Centigrade, Final time=6 minutes        -   Leading assumptions: 12 seconds per sniff, GC air adds to            sample dilution

EXAMPLES

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is thereforeintended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

Example 1 Synthesis of Table 1 Molecules

Synthesis of Table 1 Molecule Nos. 1, 3, 15, 18, 19, 20, 38, 41, 48, 50,56, 62, 63, 65, 66, 93 & 94:

applied scale (mmol No. R¹ R² X substrate) 1 Me

Cl 66 3 2R¹ = cyclopropyl

Br 67 15 Me

Cl 11 18 H

Cl 12 19 Me, H

Cl 12 20 2R¹ = cyclopropyl

Cl 12 38 H

Br 33 41 Me, H

Br 22 48 Me

I 72 50 2R¹ = cyclobutyl

I 62 56 2R¹ = cyclopropyl

I 71 62 H

I 59 63 Me, H

I 48 65

Br 11 66

I 49 93

I 49 94

I 15 Used for synthesis of molecule 45 2R¹ = cyclopropyl

Br 54

A representative procedure is provided for the synthesis of Table 1Molecule No. 50.

A solution of n-butyllithium (2.2M in cyclohexane 1 eq.) was added dropwise to an ice cold solution of diisopropylamine (1 eq.) in dry THF (0.5M). After stifling for 10 minutes at this temperature,cyclobutanecarbonitrile (1 eq.) was added to the mixture.5-Iodo-2-methylpent-2-ene (1 eq.) was added after another mixing of 10minutes at 0° C. Reaction conversion was followed by GC-MS and seen ascomplete after 15 minutes stirring at 0° C. The reaction was quenched byaddition of a saturated NH₄Cl aqueous solution and extracted with Et₂O.The combined organic layers were dried over MgSO₄ and concentrated underreduced pressure. The resulting oil was purified using a quickfiltration over silica by elution with a petroleum ether-Et₂O mixture(9-1). Concentration of the eluent under reduced pressure resulted inthe compound as a colorless oil (97% yield).

Synthesis of Table 1 Molecule Nos. 2, 10, 11, 22, 61:

applied scale (mmol No. R¹ R² X substrate) 2 Me

52 10 Me

Br 12 11 H

Br 6 22 Me

I 54 61 Me

I 27

Synthesis of Table 1 Molecule Nos. 4, 12, 13, 14, 23, 49, 52, 57, 58 &67:

applied scale (mmol No. Nitrile R¹ R² R³ R⁴ substrate) 4 1 Me Me

Me 20 12 2 Me

s-Bu 8 13 3 R¹R² = cyclopropyl

Me 12 14 3 R¹R² = cyclopropyl

n-Bu 17 23 22 Me

n-Bu 22 49 48 Me Me

Me 23 52 50 R¹R² = cyclobutyl

Me 25 57 56 R¹R² = cyclopropyl

Me 24 58 56 R¹R² = cyclopropyl

n-Bu 10 67 66 Me

Me 21

A representative procedure is given for the synthesis of Table 1Molecule No. 67.

A methyllithium solution (1.2 equiv.) was added drop wise to a solutionof the nitrile (1 eq.) in dry THF (0.5M) at −20° C. After stifling for15 minutes at −10/−20° C., full conversion was observed by GC-MS. Thereaction was quenched with a H₂SO₄ solution (2M 2 eq.) and stirred atambient temperature till full hydrolysis of the in situ formed imine wasobserved. The mixture was then extracted with Et₂O and washed with asaturated NaHCO₃ aqueous solution. The combined organic phases weredried over MgSO₄ and concentrated under reduced pressure. The resultingoil was purified using a quick filtration over silica gel by elutingwith a petroleum ether Et₂O mixture (9-1). Concentration of the eluentunder reduced pressure resulted in the compound as a colorless oil (94%yield).

Synthesis of Table 1 Molecule Nos. 5, 8, 9, 16, 21, 24, 30, 51, 54, 59 &68:

applied scale Carbonyl (mmol No. Compound R¹ R² R³ R⁴ substrate) 5 4 MeMe

Me 10 8 7 Me

H 11 9 6 Me Me

H 10 16 14 R¹R² = cyclopropyl

n-Bu 8 21 17 Me Me

H 8 24 23 Me

n-Bu 9 30 29 H H

Me 7 51 49 Me Me

Me 21 54 52 R¹R² = cyclobutyl

Me 12 59 57 R¹R² = cyclopropyl

Me 11 68 67 Me

Me 10

A representative procedure is given for the synthesis of Table 1Molecule No. 68.

To a solution of compound 67 (1 eq.) in dry THF (0.5 M) was addedportion wise lithium-aluminiumhydride (0.5 eq.) at 0° C. Reactioncompletion was observed by GC-MS after 15 minutes of stifling at ambienttemperature. The mixture was cooled to 0° C. and consequently was added:water (same amount of mL as mg hydride used), 15% NaOH solution (sameamount of mL as mg hydride used) & water (2 times amount of mL as mghydride used). This quenching was followed by stirring for 1 hour atambient temperature. The resulting mixture was filtered over celite andthe filter was washed with Et₂O. Concentration of the filtrate underreduced pressure resulted in the compound as a colorless oil (100%yield).

Synthesis of Table 1 Molecule Nos. 6, 7, 17, 39, 40, 42, 45, 53, 64 &69:

applied scale (mmol No. Nitrile R¹ R² R³ substrate) 6 1 Me Me

22 7 2 Me

23 17 15 Me Me

18 39 18 H H

17 40 38 H H

19 42 41 Me H

9 45 Described in ketone synthesis R¹R² = cyclopropyl

51 53 50 R¹R² = cyclobutyl

12 64 61 Me

9 69 66 Me

12

A representative procedure is given for the synthesis of Table 1Molecule No. 40.

To a solution of compound 38 (1 eq.) in dry CH₂Cl₂ (0.5 M) at −60° C.was added drop wise a diisobutylaluminiumhydride (1.3 eq.) solution (1.1M cyclohexane). The resulting mixture was allowed to warm to ambienttemperature for 2 hours. Reaction completion was observed by GC-MS.

The mixture was cooled to 0° C. and a saturated aqueous sodium potassiumtartrate solution was added carefully. This quenching was followed bystirring for 2 hours at ambient temperature. The resulting mixture wasextracted with CH₂Cl₂, dried over MgSO₄ and reduced under reducedpressure to yield the pure aldehyde (99% yield).

Synthesis of carboxylic acids used for the synthesis of Table 1 MoleculeNos. 26, 27, 28, 29, 30, 31, 32, 33, 37 & 60:

applied scale (mmol No. R substrate) Used for synthesis molecules 26 &27

57 Used for synthesis molecules 28, 29, 30 & 37

46 Used for synthesis molecules 31, 32, 33 & 60

209

To a solution of the phosphonium bromide[50889-29-7] (1.2 eq.) in dryTHF (0.3 M) was added KHMDS (Potassiumhexamethyldisilazane 2.4 eq.) atambient temperature. After stifling for 30 minutes at the sametemperature, a solution of ketonealdehyde (1 eq.) in dry THF (0.3 M) wasadded drop wise. The mixture was stirred for 3 hours, quenched withwater (0.3 M) and extracted with Et₂O. The resulting water layer wasacidified with a HCl aqueous solution (10%) till pH 2 was obtained. Thismixture was extracted with Et₂O and the extracts were dried over MgSO₄and concentrated under reduced pressure. The resulting oil was purifiedusing a quick filtration over silica gel by eluting with a petroleumether Et₂O mixture (1-1). Concentration under reduced pressure resultedin the compound as a slightly yellow oil. (90-95% yield).

Synthesis of Table 1 Molecule Nos. 26, 27, 28, 29 & 60:

Step 1.

Step 2.

applied scale (mmol No. R¹ R² M substrate) 26

Me MgBr 11 27

Et MgBr 9 28

Et MgBr 11 29

Me MgBr 23 60

Me Li 25

Step 1.

To a solution of the acid formed in step 1 (1 eq.) in dry CH₂Cl₂ (0.5 M)was added 1,1′-carbonyldiimidazole (1 eq.) at ambient temperature. Themixture was stirred for 15 minutes and N,O-Dimethylhydroxylaminehydrochloride (1 eq.) was added. Stirring was continued at the sametemperature for 1 hour and the mixture was quenched with an aqueous HClsolution (1 M 1.1 eq.). The aqueous layer was extracted with Et₂O,washed with NaHCO₃ and dried over MgSO₄. Concentration under reducedpressure resulted in the compound as a colorless oil. (86-95% yield)

Step 2.

The Weinreb amide formed in step 2 was solved in dry THF (0.5 M) andcooled to −15° C. A solution of cyclopropylmagnesium bromide (preparedfrom cyclopropyl bromide and magnesium turnings in THF 2 eq.) was addeddrop wise to the mixture. Complete reaction conversion was observed withGC-MS after 30 minutes stifling at 0° C. This reaction mixture wasquenched with a saturated aqueous NH₄Cl solution, extracted with Et₂O;dried over MgSO₄ and concentrated under reduced pressure. The resultingoil was purified using a quick filtration over silica gel by elutingwith a petroleum ether Et₂O mixture (9-1). Concentration under reducedpressure resulted in the compound as a colorless oil. (62-75% yield)

Synthesis of Table 1 Molecule Nos. 31, 32, 33 & 37:

applied scale (mmol No. R¹ R² substrate) 31

n-Pr 13 32

Me 13 33

Et 13 37

Me 9

A representative procedure is given for the synthesis of Table 1Molecule No. 37.

A solution of the carboxylic acid (1 eq.), methanol (2 eq.) and theIshihara catalyst dimesitylammoniumpentafluorobenzenesulfonate[850629-65-1] (1 mol %) in heptane (0.5 M)was heated at 60° C. Reaction completion was observed by GC-MS after 3hours stifling. The mixture was then washed with an aqueous HCl solution(1 M). The organic phase was dried over MgSO₄ and concentrated underreduced pressure. The resulting oil was purified using a quickfiltration over silica gel by eluting with a petroleum ether Et₂Omixture (9-1). Concentration of the eluent under reduced pressureresulted in the compound as a colorless oil (93% yield).

Synthesis of Table 1 Molecule Nos. 34, 44 & 55:

applied scale (mmol No. Alcohol R R¹ X substrate) 34

Br 8 44 43

Me I 9 55 51

Me I 10

A representative procedure is given for the synthesis of Table 1Molecule No. 55.

To a solution of alcohol 51 (1 eq.) in dry THF (0.5 M) was added sodiumhydride (1.1 eq.) and iodomethane (1.5 eq.) at 0° C. The resultingmixture was allowed to stir at ambient temperature for 3 hours. Thereaction was quenched with an aqueous saturated solution of ammoniumchloride and subsequently extracted with Et₂O. The combined organicphases were dried over MgSO₄ and reduced under reduced pressure. Theresulting oil was purified using a quick filtration over silica gel byeluting with a petroleum ether Et₂O mixture (9-1). Concentration underreduced pressure resulted in the compound as a colorless oil (99%yield).

Synthesis of Table 1 Molecule No. 25:

To a solution of sodium hydride (1 eq.) and di-iso-propylamine (1 eq.)in dry THF (0.5 M), was added drop wise propionic acid (1 eq.) at 0° C.The resulting mixture was stirred for 10 minutes at ambient temperatureand successively cooled to 0° C. again. Drop wise addition ofn-butyllithium (1 eq., 2.2 M cyclohexene) was followed by stifling atreflux temperature for 5 minutes. The mixture was cooled to 0° C. andprenyl bromide was added. Stirring for 1 hour resulted in fullconversion of the acid. The reaction was quenched with ice cold water(same amount as THF) and extracted with diethyl ether. The water layerwas treated with an aqueous HCl solution (5 M) till pH 2 and againextracted with diethyl ether. The combined organic phases were driedover MgSO₄ and concentrated under reduced pressure to yield the pureacid (100% yield).

A solution of the carboxylic acid (1 eq.), i-butanol (2 eq.) and theIshihara catalyst dimesitylammoniumpentafluorobenzenesulfonate[850629-65-1] (1 mol %) in heptane (0.5 M)was heated at 60° C. Reaction completion was observed by GC-MS after 3hours stirring.

The mixture was then washed with an aqueous HCl solution (1 M). Theorganic phase was dried over MgSO₄ and concentrated under reducedpressure. The resulting oil was purified using a quick filtration oversilica gel by eluting with a petroleum ether Et₂O mixture (9-1).Concentration of the eluent under reduced pressure resulted in thecompound as a colorless oil (89% yield).

Synthesis of Table 1 Molecule Nos. 35 & 36:

A representative procedure is given for the synthesis of Table 1Molecule No. 35.

An n-butyllithium solution (1.2 eq., 2.2 M cyclohexane) was added dropwide to a solution of acetonitrile (1.25 eq.) in dry THF at −60° C.After stirring for 15 minutes, (−)-myrtenal (1 eq.) was added to thismixture and subsequently stirred for 30 minutes at ambient temperature.Magnesium bromide (1.1 eq.) was added to this mixture followed bystifling for 15 minutes at the same temperature. Hereafter, a solutionof methylmagnesium bromide was added and stirred finally for 1 hour atambient temperature. The reaction was quenched with a saturated aqueousNH₄Cl solution and extracted with diethyl ether. The combined organicphases were dried over MgSO₄ and concentrated under reduced pressure.The resulting oil was purified using a quick filtration over silica gelby eluting with a petroleum ether Et₂O mixture (9-1). Concentration ofthe eluent under reduced pressure resulted in the compound as acolorless oil (86% yield).

Synthesis of Table 1 Molecule No. 43:

To a solution of (−)-myrtenol (1 eq.) and di-iodomethane (3 eq.) in drytoluene, was added drop wise a solution of diethyl zinc (1 M) at −50° C.Full conversion was observed within 2 hours stirring at ambienttemperature. The reaction was quenched at 0° C. by the addition of anaqueous HCl solution (1 M) and extracted with diethyl ether. Thecombined organic phases were dried over MgSO₄ and concentrated underreduced pressure. The resulting oil was purified using a quickfiltration over silica gel by eluting with a petroleum ether Et₂Omixture (9-1). Concentration of the eluent under reduced pressureresulted in the compound as an orange oil (99% yield).

Synthesis of Table 1 Molecule Nos. 46 & 47:

A representative procedure is given for the synthesis of Table 1Molecule No. 47.

A mixture of the aldehyde 45 (1 eq.), ethanediol (1.2 eq.) and thecatalyst Zirconium(IV) oxychloride octahydrate (5 mol %) in cyclohexane(0.5 M) was heated to reflux in a Dean-Stark apparatus for 5 hours togive full conversion. The reaction was quenched by the addition of anaqueous NH₄Cl solution and extracted with diethyl ether. The combinedorganic phases were dried over MgSO₄ and concentrated under reducedpressure. The resulting oil was purified using a quick filtration oversilica gel by eluting with a petroleum ether Et₂O mixture (9-1).Concentration of the eluent under reduced pressure resulted in thecompound as an orange oil (89% yield). Synthesis of Table 1 Molecule No.70:

A solution of ethyl vanillin (1 eq., 18 mmol) and hydroxylaminehydrochloride (1.2 eq.) in acetonitrile (1 M) was stirred for 1 h 30 atreflux temperature. The reaction was quenched with water and extractedwith diethyl ether. The organic layers were washed with a saturatedaqueous NaHCO₃ solution, dried over MgSO₄ and concentrated under reducedpressure. Recrystallization from di-iso-propyl ether delivered the purenitrile as white crystals (85% yield).

Synthesis of Table 1 Molecule No. 71:

A methyllithium solution (2.1 equiv., 6 mmol) was added drop wise to asolution of the nitrile 70 (1 eq.) in dry THF (0.5M) at −20° C. Afterstirring for 1 hour at ambient temperature, full conversion was observedby GC-MS. The reaction was quenched with a H₂SO₄ solution (2M 2 eq.) andstirred at ambient temperature till full hydrolysis of the in situformed imine was observed (2 hours). The mixture was then extracted withEt₂O and washed with a saturated NaHCO₃ aqueous solution. The combinedorganic phases were dried over MgSO₄ and concentrated under reducedpressure. Recrystallization from di-iso-propyl ether delivered the pureketone as white crystals (91% yield).

Synthesis of Table 1 Molecule No. 72:

A methylmagnesium bromide solution (2.5 equiv., 3 M) was added drop wiseto a solution of ethyl vanillin (1 eq., 30 mmol) in dry THF (0.25M) at0° C. After stirring for 1 hour at ambient temperature, full conversionwas observed by GC-MS. The reaction was quenched with a NH₄Cl solutionand extracted with Et₂O, dried over MgSO₄ and concentrated under reducedpressure. Recrystallization from di-iso-propyl ether delivered the pureketone as white crystals (67% yield).

Synthesis of Table 1 Molecule Nos. 75, 76, 77, 78, 79, 80, 81, 82, 83,85, 86, 90 & 91:

applied scale (mmol No. R R′ R″ R₁ R₂ R₃ R₄ R₅ R₆ substrate) 75 O O H —— Me H H H 12 76 O O H — — H H Me Me 12 77 O O H — — Me Me H H 12 78 O OH Et H — — — — 12 79 O O H Me H — — — — 12 80 O O H Me Me — — — — 12 81O O H t-Bu H — — — — 12 82 O O H H H — — — — 12 83 O O H — — H H H H 1285 O S H H H — — — — 12 86 O O H n-Bu H — — — — 12 90 O O Me Me H — — —— 12 91 O O Me Me Me — — — — 12

A representative procedure is given for the synthesis of Table 1Molecule No. 77.

A mixture of the aldehyde (1 equiv.), the diol (or thio glycol molecule85) (2 equiv.) and the catalyst ZrOCl₂.8H₂O (0.05 equiv.) in toluene(0.5 M) was refluxed under Dean-Stark conditions till full conversionwas observed by GC-MS analysis (1 to 2 h). The resulting reactionmixture was concentrated under reduced pressure and re-dissolved inEt₂O. This ether layer was washed with a saturated NaHCO₃ aqueoussolution, dried over MgSO₄ and concentrated under reduced pressure.Toluene residues were removed under high vacuum which resulted in thepure compound (99% yield).

Synthesis of Table 1 Molecule No. 73:

To a mixture of delta-damascone (1 equiv. 104 mmol) and NaHCO₃ (1equiv.) in CH₂Cl₂ (0.2M) was added meta-chloroperbenzoic acid (1.1equiv.) at 0° C. The resulting reaction mixture was stirred at ambienttemperature for 2 hours. Full conversion was observed by GC-MS analysis.The mixture was washed twice with water and filtered over a path ofCelite®, which was rinsed with CH₂Cl₂. The organic phase wasconcentrated under reduced pressure to yield the epoxide 73 (99% yield).

Synthesis of Table 1 Molecule No. 74:

To a solution of the epoxide (1 equiv. 15 mmol) in MeOH (0.5 M) wasadded methane-sulfonic acid (0.01 equiv.) at ambient temperature. Theresulting mixture was stirred at the same temperature for 9 hours. Fullconversion was observed by GC-MS analysis. The mixture was quenched bythe addition of 10 mL of a saturated NaHCO₃ aqueous solution andextracted with Et₂O. The organic layer was dried over MgSO₄ andconcentrated under reduced pressure to yield the pure product (76%yield).

Synthesis of Table 1 Molecule No. 92:

Step 1. A mixture of the epoxide table 1 molecule number (1 equiv. 19mmol), NaI (3 equiv.), CeCl₃.7H₂O (1.2 equiv.) in acetonitrile (0.5 M)was stirred at 40° C. for 2 hours. Full conversion was observed byGC-MS. The reaction was quenched by the addition of water and extractedwith Et₂O. The organic phase was washed with an aqueous Na₂S₂O₃solution, dried over MgSO₄ and concentrated under reduced pressure. Thisyielded the pure product (70% yield).

Step 2. A catalytic amount of DMAP (0.05 equiv.) was added to a mixtureof the iodohydrine (1 equiv. 10 mmol), pyridine (1.5 equiv.) and aceticanhydride (2 equiv.) in CH₂Cl₂ (0.5 M) at ambient temperature. Fullconversion was observed after 1 hour by GC-MS analysis. The reaction wasquenched by the addition of water and extracted with Et₂O. The organicphase was washed with an aqueous 1M HCl solution, dried over MgSO₄ andconcentrated under reduced pressure. This yielded the pure product (95%yield).

Step 3. A solution of the iodide (1 equiv.-15 mmol) and DBU (2 equiv.)in toluene (0.5 M) was stirred for 2 hours at 70° C. Full conversion wasobserved by GC-MS analysis. The reaction was concentrated under reducedpressure and retaken in Et₂O, washed with an aqueous 1M HCl solution,dried over MgSO₄ and again concentrated under reduced pressure. Thisresulted in pure allylic acetate (96% yield).

Step 4. An aqueous solution of NaOH (0.3 M 2N solution) was added to asolution of the acetate (1 equiv.) in THF (0.5 M) at ambienttemperature. This mixture was heated to 60° C. and stirred over night toyield full conversion (GC-MS). The reaction mixture was extracted withEt₂O, washed with water, dried over MgSO₄ and concentrated under reducedpressure. Purification by column chromatography (eluens: petroleumetherEt₂O 11) yielded the pure product (62% yield).

Synthesis of Table 1 Molecule Nos. 84 & 87:

applied scale No. R (mmol substrate) 84 n-Bu 15 87 n-pentyl 15

A representative procedure is given for the synthesis of Table 1Molecule No. 84.

A mixture of n-BuOH (1.3 M 12 mL) and sodium metal (4 eq.) was heated at110° C. till all sodium was dissolved. DMF (1.3 M 12 mL) was added tothis mixture at ambient temperature and degassed under reduced pressure.CuCl (1.45 equiv.) was added and stirred for 10 minutes at the sametemperature. After adding the bromide (1 equiv.), the mixture was heatedto 120° C. Full conversion was observed after 30 minutes by GC-MSanalysis. The resulting reaction mixture was acidified with an aqueoussolution of HCl (2 M), extracted with EtOAc, washed with water and driedover MgSO₄. Concentration under reduced pressure resulted in a brown oilwhich was purified by column chromatography (eluens: petroleumether/EtOAc—82). The product was isolated as a yellow oil (77% yield).

Synthesis of Table 1 Molecule No. 88:

To a suspension of ethyl vanillin (1 equiv. 120 mmol) and iodomethane(1.5 equiv.) in an aqueous NaOH solution (1 M 5 N solution) was addedphase transfer catalyst Aliquat 336 (0.1 equiv.). The mixture wasrefluxed for 1 hour which resulted in full conversion, observed by GC-MSanalysis. By cooling the mixture to 0° C. under continuously stirring, awhite precipitate formed. Filtration of the precipitate andrecrystallization from i-Pr₂O yielded the product as white crystals (74%yield).

Synthesis of Table 1 Molecule No. 89:

A mixture of the aldehyde table 1 molecule number 88 (1 equiv. 22 mmol)and hydroxylamine hydrochloride (1.4 equiv.) in acetonitrile (1 M) wasrefluxed for 2 hours, which resulted in full conversion observed byGC-MS analysis. The reaction was quenched by the addition of water (40mL) and extracted with Et₂O. Concentration of the organic phase underreduced pressure was followed by a recrystallization from i-Pr₂O. Thisresulted in the pure nitrile (54% yield).

Example 2 Preformed Amine Reaction Product

The following ingredients are weighted off in a glass vial:

-   -   1. 50% of the perfume material comprising one or more Table 1        PRMs    -   2. 50% of Lupasol WF (CAS#09002-98-6) from BASF, is put at        60° C. in warm water bath for 1 hour before use.

Mixing of the two ingredients is done by using the Ultra-Turrax T25Basic equipment (from IKA) during 5 minutes. When the mixing is finishedthe sample is put in a warm water bath at 60° C. for ±12 hours. Ahomogenous, viscous material is obtained.

In the same way as described above different ratios between thecomponents can be used:

Weight % Perfume Material 40 50 60 70 80 Lupasol WF 60 50 40 30 20

Example 3 84 wt % Core 16 wt % Wall Melamine Formaldehyde (MF) Capsule(PAD Reservoir System

25 grams of butyl acrylate-acrylic acid copolymer emulsifier (ColloidC351, 25% solids, pka 4.5-4.7, (Kemira Chemicals, Inc. Kennesaw, Ga.U.S.A.) is dissolved and mixed in 200 grams deionized water. The pH ofthe solution is adjusted to pH of 4.0 with sodium hydroxide solution. 8grams of partially methylated methylol melamine resin (Cymel 385, 80%solids, (Cytec Industries West Paterson, N.J., U.S.A.)) is added to theemulsifier solution. 200 grams of perfume oil comprising one or moreTable 1 PRMs is added to the previous mixture under mechanical agitationand the temperature is raised to 50° C. After mixing at higher speeduntil a stable emulsion is obtained, the second solution and 4 grams ofsodium sulfate salt are added to the emulsion. This second solutioncontains 10 grams of butyl acrylate-acrylic acid copolymer emulsifier(Colloid C351, 25% solids, pka 4.5-4.7, Kemira), 120 grams of distilledwater, sodium hydroxide solution to adjust pH to 4.8, 25 grams ofpartially methylated methylol melamine resin (Cymel 385, 80% solids,Cytec). This mixture is heated to 70° C. and maintained overnight withcontinuous stirring to complete the encapsulation process. 23 grams ofacetoacetamide (Sigma-Aldrich, Saint Louis, Mo., U.S.A.) is added to thesuspension. An average capsule size of 30 um is obtained as analyzed bya Model 780 Accusizer.

Example 4 Process of Making a Polymer Assisted Delivery (PAD) MatrixSystem

A mixture comprising 50% of a perfume composition comprising one or moreTable 1 PRMs, 40% of carboxyl-terminated Hycar®1300X18(CAS#0068891-50-9) from Noveon, (put at 60° C. in warm water bath for 1hour before mixing) and 10% of Lupasol® WF (CAS#09002-98-6) from BASF(put at 60° C. in warm water bath for 1 hour before mixing). Mixing isachieved by mixing for five minutes using a Ultra-Turrax T25 Basicequipment (from IKA). After mixing, the mixture is put in a warm waterbath at 60° C. for ±12 hours. A homogenous, viscous and sticky materialis obtained.

In the same way as described above different ratios between thecomponents can be used:

Weight % Perfume composition 40 50 60 70 80 Lupasol ® WF 12 10 8 6 4Hycar ® 48 40 32 24 16 CTBN1300X18

Weight % Perfume composition 50 50 50 50 50 50 50 50 Lupasol ® WF 2.5 57.5 10 12.5 15 17.5 20 Hycar ® CTBN 47.5 45 42.5 40 37.5 35 32.5 301300X18

Example 5 Product Formulation

Non-limiting examples of product formulations containing PRMs disclosedin the present specification perfume and amines summarized in thefollowing table.

EXAMPLES (% wt) XI XII XIII XIV XV XVI XVII XVIII XIX XX FSA^(a) 1416.47 14 12 12 16.47 — — 5 5 FSA^(b) — 3.00 — — — FSA^(c) — — 6.5 — —Ethanol 2.18 2.57 2.18 1.95 1.95 2.57 — — 0.81 0.81 Isopropyl — — — — —— 0.33 1.22 — — Alcohol Starch^(d) 1.25 1.47 2.00 1.25 — 2.30 0.5 0.700.71 0.42 Amine* 0.6 0.75 0.6 0.75 0.37 0.60 0.37 0.6 0.37 0.37 PerfumeX^(e) 0.40 0.13 0.065 0.25 0.03 0.030 0.030 0.065 0.03 0.03 Phase 0.210.25 0.21 0.21 0.14 — — 0.14 — — Stabilizing Polymer^(f) Suds — — — — —— — 0.1 — — Suppressor^(g) Calcium 0.15 0.176 0.15 0.15 0.30 0.176 —0.1- — — Chloride 0.15 DTPA^(h) 0.017 0.017 0.017 0.017 0.007 0.007 0.20— 0.002 0.002 Preservative 5 5 5 5 5 5 — 250^(j) 5 5 (ppm)^(i, j)Antifoam^(k) 0.015 0.018 0.015 0.015 0.015 0.015 — — 0.015 0.015 Dye 4040 40 40 40 40 11 30-300 30 30 (ppm) Ammonium 0.100 0.118 0.100 0.1000.115 0.115 — — — — Chloride HCl 0.012 0.014 0.012 0.012 0.028 0.0280.016 0.025 0.011 0.011 Structurant^(l) 0.01 0.01 0.01 0.01 0.01 0.010.01 0.01 0.01 0.01 Additional 0.8 0.7 0.9 0.5 1.2 0.5 1.1 0.6 1.0 0.9Neat Perfume Deionized † † † † † † † † † † Water ^(a)N,N-di(tallowoyloxyethyl)-N,N-dimethylammonium chloride. ^(b) Methylbis(tallow amidoethyl)2-hydroxyethyl ammonium methyl sulfate. ^(c)Reaction product of Fatty acid with Methyldiethanolamine in a molarratio 1.5:1, quaternized with Methylchloride, resulting in a 1:1 molarmixture of N,N-bis (stearoyl-oxy-ethyl) N,N-dimethyl ammonium chlorideand N-(stearoyl-oxy-ethyl) N,-hydroxyethyl N,N dimethyl ammoniumchloride. ^(d) Cationic high amylose maize starch available fromNational Starch under the trade name CATO ®. ^(e) Perfume comprising oneor more Table 1 PRMs. ^(f) Copolymer of ethylene oxide and terephthalatehaving the formula described in US 5,574,179 at co1.15, lines 1-5,wherein each X is methyl, each n is 40, u is 4, each R1 is essentially1,4-phenylene moieties, each R2 is essentially ethylene, 1,2-propylenemoieties, or mixtures thereof. ^(g) SE39 from Wacker ^(h)Diethylenetriaminepentaacetic acid. ^(i) KATHON ® CG available from Rohmand Haas Co. “PPM” is “parts per million.” ^(j) Gluteraldehyde ^(k)Silicone antifoam agent available from Dow Corning Corp. under the tradename DC2310. ^(l) Hydrophobically-modified ethoxylated urethaneavailable from Rohm and Haas under the tradename Aculan 44. *One or morematerials comprising an amine moiety as disclosed in the presentspecification. † balance

Example 6 Dry Laundry Formulations

% w/w granular laundry detergent composition Component A B C D E F GBrightener 0.1 0.1 0.1 0.2 0.1 0.2 0.1 Soap 0.6 0.6 0.6 0.6 0.6 0.6 0.6Ethylenediamine disuccinic acid 0.1 0.1 0.1 0.1 0.1 0.1 0.1Acrylate/maleate copolymer 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Hydroxyethanedi(methylene 0.4 0.4 0.4 0.4 0.4 0.4 0.4 phosphonic acid) Mono-C12-14alkyl, di-methyl, 0.5 0.5 0.5 0.5 0.5 0.5 0.5 mono-hydroyethylquaternary ammonium chloride Linear alkyl benzene 0.1 0.1 0.2 0.1 0.10.2 0.1 Linear alkyl benzene sulphonate 10.3 10.1 19.9 14.7 10.3 17 10.5Magnesium sulphate 0.4 0.4 0.4 0.4 0.4 0.4 0.4 Sodium carbonate 19.519.2 10.1 18.5 29.9 10.1 16.8 Sodium sulphate 29.6 29.8 38.8 15.1 24.419.7 19.1 Sodium Chloride 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Zeolite 9.6 9.48.1 18 10 13.2 17.3 Photobleach particle 0.1 0.1 0.2 0.1 0.2 0.1 0.2Blue and red carbonate speckles 1.8 1.8 1.8 1.8 1.8 1.8 1.8 EthoxylatedAlcohol AE7 1 1 1 1 1 1 1 Tetraacetyl ethylene diamine 0.9 0.9 0.9 0.90.9 0.9 0.9 agglomerate (92 wt % active) Citric acid 1.4 1.4 1.4 1.4 1.41.4 1.4 PDMS/clay agglomerates (9.5% 10.5 10.3 5 15 5.1 7.3 10.2 wt %active PDMS) Polyethylene oxide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Enzymes e.g.Protease (84 mg/g 0.2 0.3 0.2 0.1 0.2 0.1 0.2 active), Amylase (22 mg/gactive) Suds suppressor agglomerate 0.2 0.2 0.2 0.2 0.2 0.2 0.2 (12.4 wt% active) Sodium percarbonate (having 7.2 7.1 4.9 5.4 6.9 19.3 13.1 from12% to 15% active AvOx) Additional Neat Perfume** 0.5 0.5 0.5 0.5 0.50.5 0.5 Amine* 0.1 0.5 0.0 0.01 0.02 0.00 0.07 Perfume Delivery SystemAs 0.05 0.0 0.1 0.0 0.2 0.4 0.0 Disclosed In The Present SpecificationIncluding Examples 2-4 Perfume comprising one or more 0.3 0.4 0.01 0.020.04 0.1 0.1 PRMs from Table 1 Water 1.4 1.4 1.4 1.4 1.4 1.4 1.4 Misc0.1 0.1 0.1 0.1 0.1 0.1 0.1 Total Parts 100 100 100 100 100 100 100 *Oneor more materials comprising an amine moiety as disclosed in the presentspecification. **Optional

Example 7 Liquid Laundry Formulations (HDLs)

Ingredient HDL 1 HDL 2 HDL 3 HDL 4 HDL 5 HDL 6 Alkyl Ether Sulphate 0.000.50 12.0 12.0 6.0 7.0 Dodecyl Benzene 8.0 8.0 1.0 1.0 2.0 3.0 SulphonicAcid Ethoxylated Alcohol 8.0 6.0 5.0 7.0 5.0 3.0 Citric Acid 5.0 3.0 3.05.0 2.0 3.0 Fatty Acid 3.0 5.0 5.0 3.0 6.0 5.0 Ethoxysulfated 1.9 1.21.5 2.0 1.0 1.0 hexamethylene diamine quaternized Diethylene triaminepenta 0.3 0.2 0.2 0.3 0.1 0.2 methylene phosphonic acid Enzymes 1.200.80 0 1.2 0 0.8 Brightener (disulphonated 0.14 0.09 0 0.14 0.01 0.09diamino stilbene based FWA) Cationic hydroxyethyl 0 0 0.10 0 0.200 0.30cellulose Poly(acrylamide-co- 0 0 0 0.50 0.10 0 diallyldimethylammoniumchloride) Hydrogenated Castor Oil 0.50 0.44 0.2 0.2 0.3 0.3 StructurantBoric acid 2.4 1.5 1.0 2.4 1.0 1.5 Ethanol 0.50 1.0 2.0 2.0 1.0 1.0 1, 2propanediol 2.0 3.0 1.0 1.0 0.01 0.01 Glutaraldehyde 0 0 19 ppm 0 13 ppm0 Diethyleneglycol (DEG) 1.6 0 0 0 0 0 2,3-Methyl-1,3- 1.0 1.0 0 0 0 0propanediol (M pdiol) Mono Ethanol Amine 1.0 0.5 0 0 0 0 NaOH SufficientTo pH 8 pH 8 pH 8 pH 8 pH 8 pH 8 Provide Formulation pH of: SodiumCumene 2.00 0 0 0 0 0 Sulphonate (NaCS) Silicone (PDMS) emulsion 0.0030.003 0.003 0.003 0.003 0.003 Additional Neat Perfume** 0.7 0.5 0.8 0.80.6 0.6 Amine* 0.01 0.10 0.0 0.10 0.20 0.05 Perfume comprising one or0.02 0.15 0.0 0.2 0.3 0.1 more PRMs from Table 1 Perfume Delivery System0.2 0.02 0.4 0.0 0.0 0.0 As Disclosed In The Present SpecificationIncluding Examples 2-4 Water Balance Balance Balance Balance BalanceBalance *One or more materials comprising an amine moiety as disclosedin the present specification. **Optional.

Example 8 Shampoo Formulations

Ingredient Ammonium Laureth Sulfate (AE₃S) 6.00 Ammonium Lauryl Sulfate(ALS) 10.00 Laureth-4 Alcohol 0.90 Trihydroxystearin ⁽⁷⁾ 0.10 Perfumecomprising one or more 0.60 PRMs from Table 1 Sodium Chloride 0.40Citric Acid 0.04 Sodium Citrate 0.40 Sodium Benzoate 0.25 EthyleneDiamine Tetra Acetic Acid 0.10 Dimethicone ^((9, 10, 11)) 1.00 ⁽⁹⁾ Waterand Minors (QS to 100%) Balance

Example 9 Fine Fragrance Formulations

Ingredient 1 2 3 Cyclic oligosaccharide 0 5 10 Ethanol 90 75 80 Perfumecomprising one or more 10 20 10 PRMs from Table 1

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm”.

All documents cited in the Detailed Description of the Invention are, inrelevant part, incorporated herein by reference; the citation of anydocument is not to be construed as an admission that it is prior artwith respect to the present invention. To the extent that any meaning ordefinition of a term in this document conflicts with any meaning ordefinition of the same term in a document incorporated by reference, themeaning or definition assigned to that term in this document shallgovern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is thereforeintended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed is:
 1. A perfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;1-cyclopropyl-2-(cyclopropylmethyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;4-allyl-4-methylnon-1-en-5-one; 4-allyl-4-methylnon-1-en-5-(R,S)-ol;iso-butyl 2,5-dimethylhex-4-enoate; 7-cyclopentylideneheptan-2-one;8-cyclopentylideneoctan-3-one; (E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;1-(4-methylpent-3-en-1-yl)cyclobutanecarbonitrile;3,3,7-trimethyloct-6-en-2-(R,S)-ol;1-(1-(4-methylpent-3-en-1-yl)cyclobutyl)ethanone;1-(4-methylpent-3-en-1-yl)cyclobutanecarbaldehyde;1-(R,S)-(1-(4-methylpent-3-en-1-yl)cyclobutyl)ethanol;7-(R,S)-methoxy-2,6,6-trimethyloct-2-ene;1-(4-methylpent-3-en-1-yl)cyclopropanecarbonitrile;1-(1-(4-methylpent-3-en-1-yl)cyclopropyl)ethanone;1-(1-(4-methylpent-3-en-1-yl)cyclopropyl)pentan-1-one;1-(R,S)-(1-(4-methylpent-3-en-1-yl)cyclopropyl)ethanol;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; or2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 2. A perfumecomprising, based on total perfume weight, from about 0.01% to about50%, of one or more perfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-41R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; and an optionalsolvent.
 3. A consumer product comprising, based on total consumerproduct weight, from about 0.0001% to about 25% of one or more perfumeraw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-(1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; and an adjunctingredient.
 4. A consumer product according to claim 3, said consumerproduct being a cleaning and/or treatment composition, said compositioncomprising, based on total composition weight, from about 0.0001% toabout 25% of one or more perfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; stereoisomers of Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 5. A consumer productaccording to claim 3, said consumer product being a fabric and/or hardsurface cleaning and/or treatment composition, said compositioncomprising, based on total composition weight, from about 0.00001% toabout 25% of one or more perfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1-E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl) methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl) but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl) phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 6. A consumer productaccording to claim 3, said consumer product being a detergent, saiddetergent comprising, based on total detergent weight, from about0.00001% to about 25% of one or more perfume raw material selected fromTable 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol; and stereoisomers of Table 1Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-(S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-(1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal;1-(3-ethoxy-4-hydroxyphenyl)ethanone; 3-ethoxy-4-hydroxybenzonitrile;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 7. A consumer productaccording to claim 3, said consumer product being a highly compactedconsumer product, said highly compacted consumer product comprising,based on total highly compacted consumer product weight, from about0.00001% to about 25% of one or more perfume raw material selected fromTable 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-01;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-41R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 8. A consumer productaccording to claim 7, said consumer product being a highly compacteddetergent, said highly compacted detergent comprising one or moreperfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z)(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl) but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol; 4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile;2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; stereoisomers of Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-(S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-41R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 9. A perfume deliverysystem comprising from 0.001% to about 50% of one or more perfume rawmaterial selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-01;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile; (E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile;methyl 9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl) methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile, wherein said perfumedelivery system is selected from a polymer assisted delivery system; amolecule-assisted delivery system; a fiber-assisted delivery system; anamine assisted delivery system; a cyclodextrin delivery system; a starchencapsulated accord; an inorganic carrier delivery system; or apro-perfume.
 10. A perfume delivery system according to claim 9, saidperfume delivery system being a nanocapsule or a microcapsulecomprising, based on total nanocapsule or microcapsule weight, fromabout 0.1% to about 99% of one or more perfume raw material selectedfrom Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-(S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-(1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenz aldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile;2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; stereoisomers of Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one; 2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate; 1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl) methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl) but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl) phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 11. The perfumedelivery system of claim 10, said perfume delivery system comprising,one or more perfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile;2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; stereoisomers of Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl) methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl) but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl) phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 12. A perfume deliverysystem according to claim 11, said perfume delivery system being astarch encapsulated accord.
 13. A perfume delivery system according toclaim 11, said perfume delivery system being a cyclodextrin deliverysystem comprising, based on total cyclodextrin delivery system weight,from 0.1% to about 99% of one or more perfume raw material selected fromTable 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-(S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-(1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-41,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl) but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl) phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 14. A perfume deliverysystem according to claim 11, said perfume delivery system being apolymer assisted delivery matrix system comprising, based on totalpolymer assisted delivery matrix system weight, from 0.1% to about 99%of one or more perfume raw material selected from Table 1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl) propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z)(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile;2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; stereoisomers of Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 15. A perfume deliverysystem according to claim 11, said perfume delivery system being anamine assisted delivery system, said amine assisted delivery systemcomprising, based on total amine assisted delivery system weight, from1% to about 99% of one or more perfume raw material selected from Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-(S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-41R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-(1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate;1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;((1R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl)phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenz aldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile;2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile; stereoisomers of Table1 Nos.(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanenitrile;3-cyclopropyl-2-(cyclopropylmethyl)-2-methylpropanenitrile;1-(cyclopropylmethyl)cyclo-propanecarbonitrile;(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;3,3-dimethyl-4-((S)-4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-(R,S)-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;3-cyclopropyl-2-(cyclopro-pylmethyl)-2-methylpropan-1-ol;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propan-1-ol;(R,S)-2,2-di(cyclohex-2-enyl)propanenitrile;(R,S)-2,2-di(cyclohex-2-enyl)acetonitrile;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one; 2-methyl-2-((1R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanenitrile;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-(R,S)ol;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanenitrile;(2R,S)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylpropanenitrile;1-(((1R,5S)-6,6-dimethyl-bicyclo[3.1.1]hept-2-en-2-yl)-methyl)cyclobutanecarbonitrile;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propan-1-ol;2-allyl-2-methylpent-4-enenitrile; 4-allyl-4-methylnon-1-en-5-one;4-allyl-4-methylnon-1-en-5-(R,S)-ol; iso-butyl 2,5-dimethylhex-4-enoate;7-cyclopentylideneheptan-2-one; 8-cyclopentylideneoctan-3-one;(E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-(R,S)-ol(9:1-E:Z); propyl7-methyloct-6-enoate; methyl 7-methyloct-6-enoate; ethyl7-methyloct-6-enoate; 1,5,5-trimethyl-3(R,S)-(3-methylbut-2-enyloxy)cyclohex-1-ene;(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile; methyl9-methyldec-6-enoate;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanenitrile;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;41R,2R,4R,6S)-7,7-dimethyltricyclo[4.1.1.0^(2,4)]octan-2-yl)methanol;(1R,2R,4R,6S)-2-(methoxymethyl)-7,7-dimethyl-tricyclo[4.1.1.0^(2,4)]octane;1-(3-methylbut-2-en-1-yl)cyclopropanecarbaldehyde;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxane;2-(1-(3-methylbut-2-en-1-yl)cyclopropyl)-1,3-dioxolane;2,2,6-trimethylhept-5-enenitrile; 3,3,7-trimethyloct-6-en-2-one;8-methylnon-7-en-2-one; 6-methylhept-5-enenitrile;2-(R,S),6-dimethylhept-5-enenitrile;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;2-(R,S),6-dimethyl-2-(3-methylbut-2-en-1-yl)hept-5-enenitrile;2-(R,S)-allyl-2,5-dimethylhex-4-enenitrile;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;3-allyl-3,6-dimethylhept-5-en-2-ol;2-(R,S)-allyl-2,5-dimethylhex-4-enal; 3-ethoxy-4-hydroxybenzonitrile;1-(3-ethoxy-4-hydroxyphenyl)ethanone;2-ethoxy-4-(1-(R,S)-hydroxyethyl)phenol;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl) but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxan-2-yl) phenol;4-(5,5-dimethyl-1,3-dioxan-2-yl)-2-ethoxyphenol;4-(4,4-dimethyl-1,3-(R,S)-dioxan-2-yl)-2-ethoxyphenol;2-ethoxy-4-(4-(R,S)-ethyl-1,3-(R,S)-dioxolan-2-yl)phenol;2-ethoxy-4-(4-(R,S)-methyl-1,3-(R,S)-dioxolan-2-yl)phenol;4-(4,5-(R,S)-dimethyl-1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(4-(R,S)-(tert-butyl)-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxolan-2-yl)-2-ethoxyphenol;4-(1,3-dioxan-2-yl)-2-ethoxyphenol; 3-butoxy-4-hydroxybenzaldehyde;2-ethoxy-4-(1,3-(R,S)-oxathiolan-2-yl)phenol;4-(4-(R,S)-butyl-1,3-(R,S)-dioxolan-2-yl)-2-ethoxyphenol;4-hydroxy-3-(pentyloxy)benzaldehyde; 3-ethoxy-4-methoxybenzaldehyde;3-ethoxy-4-methoxybenzonitrile;2-(3-ethoxy-4-methoxyphenyl)-4-methyl-1,3-(R,S)-dioxolane;2-(3-ethoxy-4-methoxyphenyl)-4,5-(R,S)-dimethyl-1,3-dioxolane;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;2-(R,S)-isopropyl-2,5-dimethylhex-4-enenitrile; and2-(R,S)-isopropyl-2,6-dimethylhept-5-enenitrile.
 16. A perfume deliverysystem according to claim 11, said perfume delivery system being apro-perfume amine reaction product, said pro-perfume amine reactionproduct comprising, based on total pro-perfume amine reaction productweight, from 0.1% to about 99% of one or more perfume raw materialselected from Table 1 Nos.(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-41,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;4-allyl-4-methylnon-1-en-5-one; 7-cyclopentylideneheptan-2-one;8-cyclopentylideneoctan-3-one; (E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z)(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;3,3,7-trimethyloct-6-en-2-one;1-(1-(4-methylpent-3-en-1-yl)cyclobutyl)ethanone;1-(4-methylpent-3-en-1-yl)cyclobutanecarbaldehyde;1-(1-(4-methylpent-3-en-1-yl)cyclopropyl)ethanone;1-(1-(4-methylpent-3-en-1-yl)cyclopropyl)pentan-1-one;8-methylnon-7-en-2-one;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;1-(3-ethoxy-4-hydroxyphenyl)ethanone;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;3-butoxy-4-hydroxybenzaldehyde; 4-hydroxy-3-(pentyloxy)benzaldehyde;3-ethoxy-4-methoxybenzaldehyde;(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one;stereoisomers of Table 1 Nos.(S)-3,3-dimethyl-4-(4-(prop-1-en-2-yl)cyclohex-1-enyl)butan-2-one;(S)-2,2-dimethyl-3-(4-(prop-1-en-2-yl)cyclohex-1-enyl)propanal;3-cyclopropyl-2-(cyclo-propylmethyl)-2-methylpropanal;1-cyclopropyl-2-(cyclopropylme-thyl)-2,4-(R,S)-dimethylhexan-3-one;1-(1-(cyclopropyl-methyl)cyclopropyl)ethanone;1-(1-(cyclopropylmethyl)-cyclopropyl)pentan-1-one;2-methyl-2-((1,R,S)(5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enyl)propanal;4-allyl-4-methylnon-1-en-5-one; 7-cyclopentylideneheptan-2-one;8-cyclopentylideneoctan-3-one; (E/Z)-11-methyldodec-8-en-3-one (9:1E:Z);(E/Z)-10-methylundec-7-en-2-one (9:1E:Z);(E,Z)-3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acrylonitrile;(E,Z)(R,S)-5-(4-methylcyclohex-3-enyl)hex-2-enenitrile;3-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)butanal;4-((1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2-methylbutanal;3,3,7-trimethyloct-6-en-2-one;1-(1-(4-methylpent-3-en-1-yl)cyclobutyl)ethanone;1-(4-methylpent-3-en-1-yl)cyclobutanecarbaldehyde;1-(1-(4-methylpent-3-en-1-yl)cyclopropyl)ethanone;1-(1-(4-methylpent-3-en-1-yl)cyclopropyl)pentan-1-one;8-methylnon-7-en-2-one;2,6-dimethyl-2-(4-methylpent-3-en-1-yl)hept-5-enal;3-(R,S)-allyl-3,6-dimethylhept-5-en-2-one;1-(3-ethoxy-4-hydroxyphenyl)ethanone;(E)-1-(2,4,4-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl)but-2-en-1-one;(E)-1-(5-hydroxy-4-methoxy-2,2,6-trimethylcyclohexyl)but-2-en-1-one;3-butoxy-4-hydroxybenzaldehyde; 4-hydroxy-3-(pentyloxy)benzaldehyde;3-ethoxy-4-methoxybenzaldehyde; and(E)-1-(5-hydroxy-2,2,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one.
 17. Aconsumer product comprising, based on total consumer product weight,from about 0.001% to about 20% of a perfume delivery system selectedfrom the perfume delivery systems of claims 11-17.